Electrochemical dual α,β-C(sp³)–H functionalization of cyclic N-aryl amines

Green Chemistry, Journal Year: 2023, Volume and Issue: 25(7), P. 2681 - 2689

Published: Jan. 1, 2023

Herein, a straightforward route for dual α,β-C(sp 3 )–H functionalized cyclic N -aryl amines using combination of electrocatalysis and iron catalysis is disclosed, setting the stage challenging multiple site selective C–H functionalization.

Language: Английский

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Advances in photochemical/electrochemical synthesis of heterocyclic compounds from carbon dioxide

Green Chemistry, Journal Year: 2024, Volume and Issue: unknown

Published: Jan. 1, 2024

This paper reviews progress in the photochemical/electrochemical construction of heterocyclic compounds using CO 2 , differentiating between various reaction types and elucidating their underlying mechanisms as well potential applications.

Language: Английский

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Electrochemical nickel-catalysed defluoroalkylation ofgem-difluoroalkenes with alkyl halides

Green Chemistry, Journal Year: 2023, Volume and Issue: 25(20), P. 7952 - 7958

Published: Jan. 1, 2023

Herein, a direct and efficient electrochemical method for the synthesis of monofluoroalkene products was promoted using gem -difluoroalkenes unactivated alkyl halides as starting materials with nickel catalyst.

Language: Английский

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Selective Electroreductive Hydroboration of Olefins with B₂pin₂

The Journal of Organic Chemistry, Journal Year: 2023, Volume and Issue: 88(7), P. 4569 - 4580

Published: March 21, 2023

Organoboron showed great potential in the synthesis of various high-value chemical compounds. Direct hydroboration olefins has been witnessed over time as a mainstream method for organoboron In this work, an electroreductive anti-Markovnikov approach with readily available B2pin2 to synthesize valuable compounds high chemo- and regioselectivities under metal catalyst-free conditions was reported. This protocol exhibited broad substrate scope good functional-group tolerance on styrenes heteroaromatic olefins, providing synthetically useful alkylborons efficiency even deuterium borylation products D-incorporation when CD3CN employed solvent. Furthermore, gram-scale reactions extensive functional derivatization further highlighted method.

Language: Английский

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Electrocarboxylation of CO2 with Organic Substrates: Toward Cathodic Reaction

Transactions of Tianjin University, Journal Year: 2023, Volume and Issue: 29(4), P. 254 - 274

Published: July 3, 2023

Language: Английский

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