Magnetic Circularly Polarized Luminescence with Heterometallic Molecular Cluster‐Aggregates DOI Creative Commons
Diogo A. Gálico, Muralee Murugesu

Advanced Optical Materials, Journal Year: 2024, Volume and Issue: 12(27)

Published: Aug. 5, 2024

Abstract Magnetic circularly polarized luminescence (MCPL) is a technique based on the differential emission of left and right light induced by magnetic field. This counterpart to widely explored circular dichroism. In this work, first demonstration MCPL presented in heterometallic lanthanide(III) systems using two molecular cluster aggregates, {Eu 1 Tb 19 } 3 17 . The results here indicate potential that holds for obtaining highly tuned magneto‐optical materials various applications, such as anti‐counterfeiting materials. Additionally, findings suggest interactions between ions modulate dissymmetry factor, opening possibility development tunable

Language: Английский

Solvent modulation of the morphology of homochiral gadolinium coordination polymers and its impact on circularly polarized luminescence DOI Creative Commons
Ting Hou, Chen-Chen Zhao,

Song‐Song Bao

et al.

Dalton Transactions, Journal Year: 2024, Volume and Issue: 53(9), P. 4291 - 4298

Published: Jan. 1, 2024

The morphology of Gd(NO 3 ) / R -, S -AnempH 2 assemblies is controlled by solvent. spiral bundles (R-,S-1) are CPL active with asymmetric factor 2.8 times larger than that crystals (R-,S-2), while spindle-shaped particles (R-,S-3) inactive.

Language: Английский

Citations

3
Ab initio investigations of circularly polarised luminescence in Samarium(iii)-based complexes DOI Creative Commons
Maxime Grasser, Boris Le Guennic

Physical Chemistry Chemical Physics, Journal Year: 2024, Volume and Issue: 26(8), P. 7203 - 7210

Published: Jan. 1, 2024

The present study aims to gain insight into the circularly polarised luminescence (CPL) of lanthanide complexes through angle one their elements, namely Samarium.

Language: Английский

Citations

3
Circularly polarized luminescence activity in the near infrared spectral region of a water-soluble ytterbium(iii) complex containing a conjugated chromophoric ligand DOI Creative Commons
Silvia Mizzoni, Annika Sickinger, Silvia Ruggieri

et al.

New Journal of Chemistry, Journal Year: 2024, Volume and Issue: 48(21), P. 9627 - 9636

Published: Jan. 1, 2024

A chiral Yb( iii ) complex bearing a conjugated chromophoric ligand exhibits potential as NIR-to-NIR chiroptical probe for biological purposes.

Language: Английский

Citations

3
Assembly of Homochiral Magneto-Optical Dy6 Triangular Clusters by Fixing Carbon Dioxide in the Air DOI Creative Commons
Cai‐Ming Liu, Xiang Hao, Xi-Li Li

et al.

Molecules, Journal Year: 2024, Volume and Issue: 29(14), P. 3402 - 3402

Published: July 19, 2024

A new hydrazone Schiff base bridging ligand (H

Language: Английский

Citations

3
Magnetic Circularly Polarized Luminescence with Heterometallic Molecular Cluster‐Aggregates DOI Creative Commons
Diogo A. Gálico, Muralee Murugesu

Advanced Optical Materials, Journal Year: 2024, Volume and Issue: 12(27)

Published: Aug. 5, 2024

Abstract Magnetic circularly polarized luminescence (MCPL) is a technique based on the differential emission of left and right light induced by magnetic field. This counterpart to widely explored circular dichroism. In this work, first demonstration MCPL presented in heterometallic lanthanide(III) systems using two molecular cluster aggregates, {Eu 1 Tb 19 } 3 17 . The results here indicate potential that holds for obtaining highly tuned magneto‐optical materials various applications, such as anti‐counterfeiting materials. Additionally, findings suggest interactions between ions modulate dissymmetry factor, opening possibility development tunable

Language: Английский

Citations

3