Rh(III)-Catalyzed C–H Activation of Benzamides and Chemodivergent Annulation with Benzoxazinanones: Substrate Controlled Selectivity DOI

Danqing Ji,

Xingwei Li

Organic Letters, Journal Year: 2023, Volume and Issue: 25(39), P. 7083 - 7088

Published: Sept. 25, 2023

Decarboxylative annulation of propargyl carbamates with benzamides has been realized via rhodium-catalyzed C-H bond activation under mild conditions, delivering two distinct classes heterocycles in high efficiency and selectivity substrate control. This protocol provides a direct synthetic method for the preparation functionalized 1,8-naphthyridines isoindolinones.

Language: Английский

Rh(III)-Catalyzed C–H Activation of Benzamides and Chemodivergent Annulation with Benzoxazinanones: Substrate Controlled Selectivity DOI

Danqing Ji,

Xingwei Li

Organic Letters, Journal Year: 2023, Volume and Issue: 25(39), P. 7083 - 7088

Published: Sept. 25, 2023

Decarboxylative annulation of propargyl carbamates with benzamides has been realized via rhodium-catalyzed C-H bond activation under mild conditions, delivering two distinct classes heterocycles in high efficiency and selectivity substrate control. This protocol provides a direct synthetic method for the preparation functionalized 1,8-naphthyridines isoindolinones.

Language: Английский

Citations

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