Chemical Communications,
Journal Year:
2023,
Volume and Issue:
59(82), P. 12302 - 12305
Published: Jan. 1, 2023
We
report
a
multi-resonant
thermally
activated
delayed
fluorescent
(MRTADF)
afterglow
emitter
with
unprecedented
long
emission
lifetime
>
100
ms,
full-width
at
half-maximum
<
40
nm,
and
deep-blue
color
of
CIEy
0.048.
Such
emitters
remain
rarely
achieved
would
show
potential
applications
in
multiplexed
bioimaging
high-density
information
encryption.
Physical Chemistry Chemical Physics,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Jan. 1, 2025
Recent
advances
in
organic
afterglow
materials,
especially
dopant–matrix
systems,
highlight
the
synergy
between
luminophore
design
and
matrix
function,
offering
new
opportunities
for
persistent
luminescence
future
high-value
applications.
Chemistry - A European Journal,
Journal Year:
2024,
Volume and Issue:
30(18)
Published: Jan. 25, 2024
Abstract
Blue
afterglow
constitutes
of
one
the
primary
colors
and
can
convert
into
other
through
energy
transfer.
The
reported
studies
show
fabrication
blue
emitters,
but
most
them
are
formed
by
room‐temperature
phosphorescence
mechanism
require
UVB
lights
as
excitation
source
(these
high‐energy
may
damage
organic
systems).
Here
we
report
visible‐light‐excitable
thermally
activated
delayed
fluorescence
type
(TADF‐type)
materials
via
delicate
control
excited
states
in
difluoroboron
β‐diketonate
(BF
2
bdk)
systems.
Tiny
change
substituents
BF
bdk
system
has
been
found
to
pose
significant
influence
on
state
levels
consequently
narrow
singlet‐triplet
splitting
system.
As
a
result,
both
forward
reverse
intersystem
crossing
have
accelerated,
leading
emergence
bdk's
TADF‐type
rigid
crystalline
matrices.
resultant
exhibit
emission
lifetimes
several
hundred
milliseconds,
photoluminescence
quantum
yield
(PLQY)
24.7
%
display
temperature
responsive
property.
Chemical Communications,
Journal Year:
2023,
Volume and Issue:
59(82), P. 12302 - 12305
Published: Jan. 1, 2023
We
report
a
multi-resonant
thermally
activated
delayed
fluorescent
(MRTADF)
afterglow
emitter
with
unprecedented
long
emission
lifetime
>
100
ms,
full-width
at
half-maximum
<
40
nm,
and
deep-blue
color
of
CIEy
0.048.
Such
emitters
remain
rarely
achieved
would
show
potential
applications
in
multiplexed
bioimaging
high-density
information
encryption.