Reductive cyclodimerization of chalcones: exploring the “self-adaptability” of galvanostatic electrosynthesis DOI Creative Commons

Mauro Garbini,

Andrea Brunetti, Riccardo Pedrazzani

et al.

Chemical Communications, Journal Year: 2023, Volume and Issue: 60(4), P. 404 - 407

Published: Nov. 28, 2023

The “self-adaptability” of galvanostatic electrolysis was shown to assist a multistage unprecedented chemo- and diastereoselective electrochemically promoted cyclodimerization chalcones.

Language: Английский

Polymerization-induced emission of borinic acid towards stimuli-responsive luminescent polymers DOI

Xing-Ying Zheng,

Tao Li,

Hua‐Wen Cai

et al.

Polymer, Journal Year: 2024, Volume and Issue: 300, P. 126996 - 126996

Published: April 1, 2024

Language: Английский

Citations

6
Additive‐Promoted Grignard Reagent Mediated Polymerization With Increased Radical Characteristic Yielding Polystyrene With Narrow Molecular Weight Distribution DOI Open Access
Chengjun Qiu, Junshan Lai, Xinhui Wang

et al.

Journal of Polymer Science, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 6, 2025

ABSTRACT Gaining polymer with narrow molecular weight distribution ( Đ ) by efficient living polymerization methods is fundamental and essential in science. Grignard reagent mediated anionic capable of low , however, not suitable for the nonpolar monomers like styrene (St). Here, several kinds additives lithium chloride (LiCl) N,N,N′,N′′,N′′ ‐Pentamethyldiethylenetriamine (PMDETA) are demonstrated as that can promote St. Through LiCl‐promoted polymerization, polystyrene (PS) manipulated successfully achieved under mild conditions full monomer conversion, using a series reagents (RMgX) presence LiCl. In comparison, no PS be prepared absence additive. Electron paramagnetic resonance reveals radical characteristic increased additive, which eventually enables successful St conversion. This work therefore opens simple additive strategy to current method expands library might cause inspirations chemistry.

Language: Английский

Citations

0
Moisture-Resistant Radical Anions of Quinoxalin-2(1H)-ones in Aerial Dioxygen Activation DOI

Sudip Sau,

Sathi Sahoo,

Anupam Manna

et al.

Organic & Biomolecular Chemistry, Journal Year: 2024, Volume and Issue: 22(23), P. 4662 - 4666

Published: Jan. 1, 2024

In situ generation of a stable radical anion under ambient conditions, showcasing its efficacy in activating molecular oxygen to corresponding reactive species (ROS) within the context quinoxaline-2(1 H )-one oxygenation.

Language: Английский

Citations

2
Reductive cyclodimerization of chalcones: exploring the “self-adaptability” of galvanostatic electrosynthesis DOI Creative Commons

Mauro Garbini,

Andrea Brunetti, Riccardo Pedrazzani

et al.

Chemical Communications, Journal Year: 2023, Volume and Issue: 60(4), P. 404 - 407

Published: Nov. 28, 2023

The “self-adaptability” of galvanostatic electrolysis was shown to assist a multistage unprecedented chemo- and diastereoselective electrochemically promoted cyclodimerization chalcones.

Language: Английский

Citations

5