Photogenerated charge carriers’ regulation strategies: Structure design, mechanism, and characterization technology DOI
Xuli Li, Qing Wang,

Yan Sun

et al.

International Journal of Hydrogen Energy, Journal Year: 2024, Volume and Issue: 69, P. 1341 - 1365

Published: May 14, 2024

Language: Английский

Progress in the advancement of atomically dispersed catalysts for enhanced performance lithium-sulfur batteries DOI
Jiangqi Zhou, Aiyue Sun

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 488, P. 150719 - 150719

Published: March 29, 2024

Language: Английский

Citations

15
Highly efficient recycling of polyester wastes to diols using Ru and Mo dual-atom catalyst DOI Creative Commons

Minhao Tang,

Ji Shen,

Yiding Wang

et al.

Nature Communications, Journal Year: 2024, Volume and Issue: 15(1)

Published: July 4, 2024

Abstract The chemical recycling of polyester wastes is great significance for sustainable development, which also provides an opportunity to access various oxygen-containing chemicals, but generally suffers from low efficiency or separation difficulty. Herein, we report anatase TiO 2 supported Ru and Mo dual-atom catalysts, achieve transformation polyesters into corresponding diols in 100% selectivity via hydrolysis subsequent hydrogenation water under mild conditions (e.g., 160 °C, 4 MPa). Compelling evidence provided the coexistence single-atom O-bridged sites within this kind catalysts. It verified that activate H carboxylic acid derived hydrolysis, suppress hydrodeoxygenation resultant alcohols due a high reaction energy barrier. Notably, catalysts can be regenerated with activity stability. This work presents effective way reconstruct valuable diols, may have promising application potential.

Language: Английский

Citations

15
Thermal Shock Synthesis for Loading Sub‐2 nm Ru Nanoclusters on Titanium Nitride as a Remarkable Electrocatalyst toward Hydrogen Evolution Reaction DOI
Lingbo Zong,

Fenghong Lu,

Ping Li

et al.

Advanced Materials, Journal Year: 2024, Volume and Issue: 36(32)

Published: May 19, 2024

Heterogeneous catalysts embracing metal entities on suitable supports are profound in catalyzing various chemical reactions, and substantial synthetic endeavors metal-support interaction modulation made to enhance catalytic performance. Here, it is reported the loading of sub-2 nm Ru nanocrystals (NCs) titanium nitride support (HTS-Ru-NCs/TiN) via a special Ru-Ti using high-temperature shock (HTS) method. Direct dechlorination adsorbed RuCl

Language: Английский

Citations

14
A molecular view of single-atom catalysis toward carbon dioxide conversion DOI Creative Commons
Xin Shang,

Xiaofeng Yang,

Ye Liu

et al.

Chemical Science, Journal Year: 2024, Volume and Issue: 15(13), P. 4631 - 4708

Published: Jan. 1, 2024

We present critical advances in single-atom catalysis toward CO 2 transformation and address crucial issues about SACs from a molecular point of view.

Language: Английский

Citations

13
Do we achieve “1 + 1 > 2” in dual-atom or dual-single-atom catalysts? DOI
Xue Yang,

Linyao Xu,

Yuxin Li

et al.

Coordination Chemistry Reviews, Journal Year: 2024, Volume and Issue: 516, P. 215961 - 215961

Published: May 29, 2024

Language: Английский

Citations

10
Tuning the Inter‐Metal Interaction between Ni and Fe Atoms in Dual‐Atom Catalysts to Boost CO2 Electroreduction DOI Open Access
Yang Chen,

Jia Zhao,

Xiaoli Pan

et al.

Angewandte Chemie International Edition, Journal Year: 2024, Volume and Issue: 63(44)

Published: Aug. 8, 2024

Abstract Dual‐atom catalysts (DACs) are promising for applications in electrochemical CO 2 reduction due to the enhanced flexibility of catalytic sites and synergistic effect between dual atoms. However, precisely controlling atomic distance identifying dual‐atom configuration DACs optimize performance remains a challenge. Here, Ni Fe pairs were constructed on nitrogen‐doped carbon support three different configurations: NiFe‐isolate, NiFe‐N bridge, NiFe‐bonding. It was found that bridge catalyst with NiN 4 FeN sharing two N atoms exhibited superior activity stability when compared NiFe‐isolate NiFe‐bonding catalysts. A series characterizations density functional theory calculations suggested N‐bridged NiFe an appropriate can exert more pronounced synergy. not only regulated suitable adsorption strength *COOH intermediate but also promoted desorption *CO, thus accelerating electroreduction CO. This work provides important implication enhancement catalysis by tailoring coordination structure DACs, identification neighboring

Language: Английский

Citations

10
From Single-atom to Bi-atom and Ordered Multi-atom: Not Just a Number Changing for Electrocatalysis DOI
Wenting Lu, Xiao Zhao

Chemical Research in Chinese Universities, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 7, 2025

Language: Английский

Citations

1
Overlooked Synergistic Effect Induced by Fe-Mo Dual-atom Catalyst in Water Remedation: Enhanced Electron Management and Efficient Pollutants Pre-activation DOI
Yanan Huang, Yan Zhao,

Dawei Song

et al.

Applied Catalysis B Environment and Energy, Journal Year: 2025, Volume and Issue: unknown, P. 125377 - 125377

Published: April 1, 2025

Language: Английский

Citations

1
Refining Asymmetric Low‐Coordinated Fe‐N3 Motif to Boost Catalytic Ozonation Activity DOI
Wei Qu,

Su Tang,

Zhuoyun Tang

et al.

Advanced Functional Materials, Journal Year: 2024, Volume and Issue: 34(26)

Published: Feb. 28, 2024

Abstract In the quest to boost intrinsic activity of single‐atom catalysts (SACs), optimizing electronic properties metal centers and maximizing active sites play a pivotal role. Here, facile surface molten salt‐assisted approach for fabricating porous iron‐nitrogen‐carbon enriched with catalytically accessible motifs is reported. Multiple characterization analyses prove that abundant defects are generated at edge sites, resulting in formation thermally stable unstitched Fe‐N 3 motif. Theoretical investigations unveil transition from 4 induces structural alteration, convergence Fe‐3 d orbital energy Fermi energy. The low‐coordinated motif exhibits higher activation ability, reinforcing its interaction O weakening O‐O bond. This leads reduction reactivity atomic oxygen barriers (O ‐to‐*O/*OO), ultimately achieving efficient catalytic oxidation methyl mercaptan intermediates, performance 20‐fold than intact 625‐fold commercial MnO 2 . These findings present comprehensive synthesizing SACs fully boosted configurations advance ozonation activity.

Language: Английский

Citations

8
Densely accessible Fe/Co–Nx dual-atom site coupled core–shell Co3Fe7@C as an efficient bifunctional oxygen electrocatalyst for rechargeable zinc–air batteries DOI
Katam Srinivas,

Hesheng Yu,

Zhuo Chen

et al.

Journal of Materials Chemistry A, Journal Year: 2024, Volume and Issue: 12(27), P. 16863 - 16876

Published: Jan. 1, 2024

The symmetric electronic structure of an Fe single-atom site catalyst was effectively regulated by incorporating Co–N x sites and core–shell Co 3 7 @C nanoparticles, resulting in high performance towards the ORR Zn–air batteries.

Language: Английский

Citations

8