Synlett, Journal Year: 2024, Volume and Issue: 35(17), P. 1937 - 1946
Published: May 14, 2024
Abstract The cleavage of double bonds in alkenes constitutes an integral process converting feedstock materials into high-value synthetic intermediates. Well-known examples such as the oxidative olefins and olefin metathesis only facilitate synthesis oxygen-containing compounds recombination olefins. Therefore, it is appealing to extend C=C bond yield more abundant transformations. Herein, we report a novel photocatalytic approach for deconstructive carboxylation with CO2 carboxylic acids absence transition metals. Compared reported carboxylations during which carbon numbers are typically increased, achieve exchange dioxide one carbons alkene bond, thus providing unchanged when terminal used.
Language: Английский