Ag nanoparticles induced abundant Cuδ+ sites in Cu2Se nanoflower rods to promote efficient carbon dioxide electroreduction to ethanol DOI

Zheng Tang,

Chenxi Li, Chenyu Yan

et al.

Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 679, P. 50 - 59

Published: Oct. 18, 2024

Language: Английский

Review on strategies for improving the added value and expanding the scope of CO2 electroreduction products DOI
Minghang Jiang, Huaizhu Wang, Mengfei Zhu

et al.

Chemical Society Reviews, Journal Year: 2024, Volume and Issue: 53(10), P. 5149 - 5189

Published: Jan. 1, 2024

This review summarizes promising strategies including the design of catalysts and construction coupled electrocatalytic reaction systems, aimed at achieving selective production various products from CO 2 electroreduction.

Language: Английский

Citations

75
Synergy of Ni Nanoclusters and Single Atom Site: Size Effect on the Performance of Electrochemical CO2 Reduction Reaction and Rechargeable Zn−CO2 Batteries DOI

Kanghua Miao,

Jundi Qin,

Jun Yang

et al.

Advanced Functional Materials, Journal Year: 2024, Volume and Issue: 34(33)

Published: April 18, 2024

Abstract The design of bifunctional electrocatalysts toward reduction reaction carbon dioxide (ECO 2 RR) and oxygen evolution (OER) in aqueous rechargeable Zn─CO batteries (ZABs) still poses a significant challenge. Herein, Ni clusters (Ni x ) 0.5 0.8 nm diameter coupled with single site (Ni−N 4 −C), denoted as Ni−N /Ni 5 8 , respectively, are synthesized the size effect nanoclusters studied. exhibits an ≈100% Faradaic efficiency ( FE CO ECO RR for from −0.4 to −0.8 V versus reversible hydrogen electrode, superior that −C = 55.0%) 80.0%). OER performance or comparable commercial RuO but outperform −C. Theoretical calculation indicates * COOH intermediates bond synergistically atom site, promoting activation reducing energy barrier potential determining step RR. Such is strongly size‐dependent larger result too strong binding intermediates, impede formation CO. As cathode electrocatalyst alkaline ZABs, peak power density 11.7 mW cm −2 cycling durability over 1200 cycles 420 h.

Language: Английский

Citations

28
Efficient Capture and Electroreduction of Dilute CO2 into Highly Pure and Concentrated Formic Acid Aqueous Solution DOI

Zhenhua Zhao,

Jia‐Run Huang,

Da-Shuai Huang

et al.

Journal of the American Chemical Society, Journal Year: 2024, Volume and Issue: 146(20), P. 14349 - 14356

Published: May 14, 2024

High-purity CO2 rather than dilute (15 vol %, CO2/N2/O2 = 15:80:5, v/v/v) similar to the flue gas is currently used as feedstock for electroreduction of CO2, and liquid products are usually mixed up with cathode electrolyte, resulting in high product separation costs. In this work, we showed that a microporous conductive Bi-based metal–organic framework (Bi-HHTP, HHTP 2,3,6,7,10,11-hexahydroxytriphenylene) can not only efficiently capture from under humidity but also catalyze adsorbed into formic acid current density 80 mA cm–2 Faradaic efficiency 90% at very low cell voltage 2.6 V. Importantly, performance atmosphere was close high-purity atmosphere. This first catalyst maintain exceptional eCO2RR presence both O2 N2. Moreover, by using feedstock, 1 working electrode coating Bi-HHTP continuously produce 200 mM aqueous solution relative purity 100% least 30 h membrane assembly (MEA) electrolyzer. The does contain electrolytes, such highly concentrated pure be directly an electrolyte fuel cells. Comprehensive studies revealed might ascribed ability micropores on lower Gibbs free energy formation key intermediate *OCHO open Bi sites.

Language: Английский

Citations

26
Selective Increase in CO2 Electroreduction to Ethanol Activity at Nanograin‐Boundary‐Rich Mixed Cu(I)/Cu(0) Sites via Enriching Co‐Adsorbed CO and Hydroxyl Species DOI
Ting Zhang,

Shenglin Xu,

De‐Li Chen

et al.

Angewandte Chemie International Edition, Journal Year: 2024, Volume and Issue: unknown

Published: May 31, 2024

Selective producing ethanol from CO

Language: Английский

Citations

24
Enhancing CO2 Electroreduction Performance through Si-Doped CuO: Stabilization of Cu+/Cu0 Sites and Improved C2 Product Selectivity DOI
Feng Long, Rong Wang, Wenzhe Si

et al.

ACS Catalysis, Journal Year: 2024, Volume and Issue: 14(13), P. 10324 - 10333

Published: June 25, 2024

Language: Английский

Citations

14
Identification of Synergies in Fe, Co-Coordinated Polyphthalocyanines Scaffolds for Electrochemical CO2 Reduction Reaction DOI

Zhouxin Wang,

Jun Qian, P. Y. Cao

et al.

Nano Letters, Journal Year: 2024, Volume and Issue: 24(10), P. 3249 - 3256

Published: March 4, 2024

The synergistic interaction between the isolated metal sites promoted electrocatalytic activity of catalysts. However, structural heterogeneity makes it challenging to evaluate this effect accurately. In work, metal-coordinated polyphthalocyanine molecules (Fe-PPc, Co-PPc, FeCo-PPc) with long-range ordered and precise coordination structures are used as a platform study synergies different in electrochemical CO2 reduction reaction. combination means experimental theoretical calculation clearly reveal that coexistence Fe Co PPc significantly enhances conjugation macrocycle. This enhancement subsequently causes lose more electrons, thereby improving their adsorption facilitating formation intermediate *COOH on them. As result, FeCo-PPc achieves CO partial current density about 57.4 mA/cm2 high turnover frequency over 49000 site–1 h–1 at −0.9 V (vs RHE).

Language: Английский

Citations

9
Regulating the Critical Intermediates of Dual‐Atom Catalysts for CO2 Electroreduction DOI
Mengyang Zhang,

Dingyang Zhou,

Xueqin Mu

et al.

Small, Journal Year: 2024, Volume and Issue: unknown

Published: May 27, 2024

Electrocatalysis is a very attractive way to achieve sustainable carbon cycle by converting CO

Language: Английский

Citations

7
Strategies for overcoming challenges in selective electrochemical CO2 conversion to ethanol DOI Creative Commons
Zihong Wang, Yecheng Li, Zhihao Ma

et al.

iScience, Journal Year: 2024, Volume and Issue: 27(8), P. 110437 - 110437

Published: July 2, 2024

The electrochemical conversion of carbon dioxide (CO2) to valuable chemicals is gaining significant attention as a pragmatic solution for achieving neutrality and storing renewable energy in usable form. Recent research increasingly focuses on designing electrocatalysts that specifically convert CO2 into ethanol, desirable product due its high-energy density, ease storage, portability. However, high-efficiency ethanol production remains challenge compared ethylene (a competing with similar electron configuration). Existing electrocatalytic systems often suffer from limitations such low efficiency, poor stability, inadequate selectivity toward ethanol. Inspired by recent progress the field, this review explores fundamental principles material advancements electroreduction, emphasizing strategies over ethylene. We discuss electrocatalyst design, reaction mechanisms, challenges, future directions. These aim bridge gap between current industrialized applications technology.

Language: Английский

Citations

6
Electron‐rich SnO2 promote CO2 activation for stable electrocatalytic CO2 reduction DOI

Chenyue Li,

Fei Liu,

Shuo Geng

et al.

Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 678, P. 636 - 645

Published: Sept. 19, 2024

Language: Английский

Citations

6
Carbon- and energy-efficient ethanol electrosynthesis via interfacial cation enrichment DOI
Ali Shayesteh Zeraati, Feng Li, Tartela Alkayyali

et al.

Nature Synthesis, Journal Year: 2024, Volume and Issue: unknown

Published: Oct. 4, 2024

Language: Английский

Citations

6