Cited by Heterogeneous Iron-Catalyzed Oxyalkylation of Vinylarenes via C(sp<sup>3</sup>)

Fundamental Mechanistic Insights on the Peripherally Substituted Iron Phthalocyanine Selectively Catalyzing the Sulfur Redox Reactions DOI

Yu Wang, Weijie Chen, Yu Du

et al.

Energy storage materials, Journal Year: 2025, Volume and Issue: unknown, P. 104157 - 104157

Published: March 1, 2025

Language: Английский

Citations

Oxidative amination of unactivated alkenes via nitrogen atom insertion into carbon-carbon double bonds DOI

Yannick Brägger, Ann-Sophie K. Paschke, Nima Nasiri

et al.

Published: May 20, 2024

The synthesis of nitrogen-containing molecules through C–N bond formation is critical for the discovery and preparation medicines, agrochemicals materials. Traditional synthetic methods using alkenes as ubiquitous substrates leverage reactivity C(sp2)–C(sp2) π formation. In contrast, that can form bonds complete cleavage double are scarce, despite considerable potential such a strategy. Here, we report direct insertion nitrogen atom into unactivated carbon-carbon to access aza-allenium intermediates which be converted either nitriles or amidine products, depending on initial alkene substitution pattern. This operationally simple highly functional group tolerant reaction works wide range alkenes. Our mechanistic proposal supported by chemical trapping experiments, concomitantly demonstrate utility our method valuable N-heterocycles. Overall, this study demonstrates possibility reactive (i.e. aza-alleniums), have ample downstream diversification, from alkenes, opening new avenues important products.

Language: Английский

Citations

C═C Dissociative Imination of Styrenes by a Photogenerated Metallonitrene DOI

Till Schmidt‐Räntsch, Hendrik Verplancke, Annemarie Kehl

et al.

JACS Au, Journal Year: 2024, Volume and Issue: 4(9), P. 3421 - 3426

Published: Sept. 3, 2024

Photolysis of a platinum(II) azide complex in the presence styrenes enables C=C double bond cleavage upon dissociative olefin imination to aldimido (Pt

Language: Английский

Citations

Reductive Coupling of N-Heteroarenes and 1,2-Dicarbonyls for Direct Access to γ-Amino Acids, Esters, and Ketones Using a Heterogeneous Single-Atom Iridium Catalyst DOI

Huanhuan Jia, Qi Liao, Wei Liu

et al.

Journal of the American Chemical Society, Journal Year: 2024, Volume and Issue: 146(46), P. 31647 - 31655

Published: Nov. 7, 2024

Despite their significant importance, the challenges in direct and diverse synthesis of N-heterocyclic γ-amino acids/esters/ketones hamper exploration applications. Herein, by developing a multifunctional heterogeneous iridium single-atom catalyst composed silica-confined species boron-doped ZrO

Language: Английский

Citations

Highly Efficient Electrosynthesis of Oximes from Nitrates and Carbonyl Compounds in Acidic Media DOI

Cheng Xue, Shuaiqiang Jia,

Jiapeng Jiao

et al.

Green Chemistry, Journal Year: 2024, Volume and Issue: 26(18), P. 9869 - 9873

Published: Jan. 1, 2024

Electrocatalytic nitrate reduction reaction (NO 3 RR) coupled with organic compounds to synthesize oximes for value-added conversion of waste pollutants has very promising prospects.

Language: Английский

Citations

Carbon-Chain Elongation by Co-Catalyzed Selective C–C Bond Cleavage and Subsequent Silylperoxylation of Alkene Substrates DOI

Jia‐Hao Xie, Terumasa Kato, Keiji Maruoka

et al.

ACS Catalysis, Journal Year: 2024, Volume and Issue: unknown, P. 14754 - 14761

Published: Sept. 20, 2024

Language: Английский

Citations

Heterogeneous Iron-Catalyzed Oxyalkylation of Vinylarenes via C(sp³)—H Activation of Cyclic Ethers DOI

Yu Lei,

Kang Sheng,

Ting Li

et al.

Chinese Journal of Organic Chemistry, Journal Year: 2024, Volume and Issue: 44(6), P. 1978 - 1978

Published: Jan. 1, 2024

Language: Английский

Citations