Macroscopic alignment of metal–organic framework crystals: recent advances and perspectives on sustainability DOI

Yeongseo Bak,

Taegyun Hong,

Jesse G. Park

et al.

Green Chemistry, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 6, 2024

We review in situ and post-synthetic methods for controlling the orientation of metal–organic frameworks. This highlights recent achievements approaches their implications sustainability green technologies.

Language: Английский

Ultra-thin Two-dimensional (2D) Manganese-based Metal-Organic Framework Nanosheets for Photocatalytic Selective Oxidation Thioether DOI
Jing Zhu,

Cuimeng Huo,

Jin Chen

et al.

Dalton Transactions, Journal Year: 2024, Volume and Issue: 53(37), P. 15688 - 15695

Published: Jan. 1, 2024

The efficiency of photocatalysts depends largely on the accessibility reaction species to active centre, electron transfer and geometric matching between surface catalyst species. In this work, we successfully synthesized designed one two-dimensional Mn(II) MOF with [Mn

Language: Английский

Citations

1
Photo- and Electro-chemical Strategies for Indazole Synthesis DOI Creative Commons
Binbin Huang

Tetrahedron Chem, Journal Year: 2024, Volume and Issue: unknown, P. 100116 - 100116

Published: Dec. 1, 2024

The indazole core is prevalently found in the structures of bioactive molecules, demonstrating promising potential medicinal chemistry and drug discovery, which therefore has attracted sustained attention from synthetic community. Over recent decades, significant progress been achieved both organic photocatalysis electrosynthesis, offering novel approaches for efficient sustainable synthesis various functionalized indazoles. This mini-review highlights emerging methodological advancements photo-/electro-chemical two common forms indazole, namely 1H- 2H-indazoles, are classified by specific intramolecular bond formation patterns: (1) C-C formation, (2) C-N (3) N-N formation. reaction conditions, representative scopes, mechanistic understandings these protocols emphasized, to elucidate advantages limitations current strategies, with an aim inspire future innovations that may address challenges modern synthesis.Graphical abstractTo create your abstract, type over instructions template box below. Fonts or abstract dimensions should not be changed altered.

Language: Английский

Citations

1
Dynamic covalent bonding for directed construction of molecular cages toward carbon dioxide reduction DOI

Jingting He,

Man Dong,

Yang Zhao

et al.

Inorganic Chemistry Frontiers, Journal Year: 2024, Volume and Issue: 11(16), P. 5120 - 5126

Published: Jan. 1, 2024

A strategy for customized synthesis of MOCs by constructing dynamic covalent bonds.

Language: Английский

Citations

0
Electrochemical Heteroarylation and Amidation of Alkanes using Activated Glassy Carbon Electrodes without Mediators DOI
Irene Bosque, José C. González‐Gómez,

Loris Laze

et al.

Published: Oct. 23, 2024

Abstract The functionalization of challenging unactivated C(sp3)-H bonds was achieved electrocatalytically via hydrogen atom transfer and without mediators. This possible through the sole activation surface Glassy Carbon Electrode in an electrochemical fashion using a phosphate buffer. produced oxygenated functional groups on surface, capable abstracting these atoms from alkanes. Minisci Ritter-type reactions were this procedure. Extensive characterization AGCE preliminary mechanistic studies allow us to propose plausible reaction mechanisms. Furthermore, regular battery can be used within protocol achieve desired substituted alkanes under inexpensive user-friendly conditions.

Language: Английский

Citations

0
A Protocol for Unveiling the Nature of Photocatalytic Hydrogen Evolution Reactions: True Water Splitting or Sacrificial Reagent Acceptorless Dehydrogenation? DOI
Yong Peng, Jabor Rabeah, Henrik Junge

et al.

Angewandte Chemie, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 12, 2024

Abstract Photocatalytic water splitting for hydrogen evolution is a highly topical subject in academic research and promising approach sustainable fuel production from solar energy. Due to the mismatched energy diagram of photosensitizer (especially semiconductor‐based materials where band‐edge engineering not trivial) redox potential half‐reactions splitting, photocatalytic H 2 generation usually accelerated by addition hole scavengers, i.e. sacrificial reagents such as alcohols, amines, thiols. However, source protons evolved often neglected, it questionable whether systems are really splitting. Here, we discuss recent reports on reagent‐assisted present our findings, which showcase that reagent investigated inherently undergoes acceptorless dehydrogenation, with O serving proton shuttle, amount doesn't change during course reaction.

Language: Английский

Citations

0
A Protocol for Unveiling the Nature of Photocatalytic Hydrogen Evolution Reactions: True Water Splitting or Sacrificial Reagent Acceptorless Dehydrogenation? DOI Open Access
Yong Peng, Jabor Rabeah, Henrik Junge

et al.

Angewandte Chemie International Edition, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 12, 2024

Photocatalytic water splitting for hydrogen evolution is a highly topical subject in academic research and promising approach sustainable fuel production from solar energy. Due to the mismatched energy diagram of photosensitizer (especially semiconductor-based materials where band-edge engineering not trivial) redox potential half-reactions splitting, photocatalytic H

Language: Английский

Citations

0
Macroscopic alignment of metal–organic framework crystals: recent advances and perspectives on sustainability DOI

Yeongseo Bak,

Taegyun Hong,

Jesse G. Park

et al.

Green Chemistry, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 6, 2024

We review in situ and post-synthetic methods for controlling the orientation of metal–organic frameworks. This highlights recent achievements approaches their implications sustainability green technologies.

Language: Английский

Citations

0