Highly Reversible Zn Metal Anode Securing by Functional Electrolyte Modulation

Advanced Energy Materials, Journal Year: 2024, Volume and Issue: unknown

Published: June 10, 2024

Abstract The stability of the Zn metal anode is significantly affected by various parasitic reactions during plating/stripping. Here, sodium 4‐aminobenzenesulfonate (SABS) a functional electrolyte additive to modulate electrode/electrolyte interface protect metal. An electrical double layer (EDL) reconstruction providing hydrogen bond sites through nitrogen and oxygen elements with lone pair electrons in SABS molecules. These strong bonds not only limit corrosion free H 2 O molecules on surface but also promote desolvation process. Besides, can be further situ decomposed into solid (SEI) regulate plating/stripping behavior 2+ . As result, based synergism organic–inorganic hybrid SEI EDL reconstruction, Zn//Zn symmetric cells exceptionally survive lasting for 6500 hours at 1 mA cm −2 mAh , over 900 cycles even 40 10 Zn‐I full cell maintains excellent cycle 92.4% after 20000 cycles. Remarkably, pouch capacity retention 99.1% (63 mAh) 820 5

Language: Английский

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Construction of Artificial Interface Layer in the Fly Ash Suspension for Durable Zn Anode

ACS Applied Energy Materials, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 22, 2025

Language: Английский

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Zinc‐Ion Battery Chemistries Enabled by Regulating Electrolyte Solvation Structure

Advanced Functional Materials, Journal Year: 2024, Volume and Issue: unknown

Published: May 11, 2024

Abstract Designing next‐generation alternative energy storage devices that feature high safety, low cost, and long operation lifespan is of the utmost importance for future wide range applications. Aqueous zinc‐ion batteries play a vital part in promoting development portability, sustainability, diversification rechargeable battery systems. Based on theory electrolyte solvation chemistry, deep understanding interaction between components their impact chemical properties has achieved series research progress. Analyzing shell or structure–performance relationship, establishing more stable high‐energy chemistries are inevitable requirements to suppress electrolyte–electrode interphase side reaction realize functional use batteries. In this critical review, attempt overview current comprehension regarding structure zinc technology. Advanced methodology toward interactions cations, solvent molecules, anions aqueous electrolytes general rules design from atomic level summarized. Methods viable modification then introduced overcoming remained challenges transferring laboratory results practical Possible direction with aim investigating ultimate choice high‐performance construction also outlined.

Language: Английский

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Artificial Hydrophilic Organic and Dendrite-Suppressed Inorganic Hybrid Solid Electrolyte Interface Layer for Highly Stable Zinc Anodes

ACS Applied Materials & Interfaces, Journal Year: 2024, Volume and Issue: 16(8), P. 10218 - 10226

Published: Feb. 21, 2024

Aqueous zinc-ion batteries (AZIBs) have gained significant attentions for their inherent safety and cost-effectiveness. However, challenges, such as dendrite growth anodic corrosion at the Zn anode, hinder commercial viability. In this paper, an organic-inorganic coating layer (Nafion-TiO

Language: Английский

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Multi‐Group Polymer Coating on Zn Anode for High Overall Conversion Efficiency Photorechargeable Zinc‐Ion Batteries

Angewandte Chemie International Edition, Journal Year: 2024, Volume and Issue: unknown

Published: Aug. 14, 2024

The solar-driven photorechargeable zinc-ion batteries have emerged as a promising power solution for smart electronic devices and equipment. However, the subpar cyclic stability of Zn anode remains significant impediment to their practical application. Herein, poly(diethynylbenzene-1,3,5-triimine-2,4,6-trione) (PDPTT) was designed functional polymer coating Zn. Theoretical calculations demonstrate that PDPTT not only significantly homogenizes electric field distribution on surface, but also promotes ion-accessible surface With multiple N C=O groups exhibiting strong adsorption energies, this reduces nucleation overpotential Zn, alters diffusion pathway

Language: Английский

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Engineering interfaces of zinc metal anode for stable batteries

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 491, P. 152050 - 152050

Published: May 8, 2024

Language: Английский

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Strategies of regulating Zn2+ solvation structures toward advanced aqueous zinc-based batteries

Energy storage materials, Journal Year: 2024, Volume and Issue: 70, P. 103451 - 103451

Published: May 11, 2024

Language: Английский

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A Water‐Insoluble Yttrium‐Based Complex as Dual‐Ionic Electrolyte Additive for Stable Aqueous Zinc Metal Batteries

Advanced Functional Materials, Journal Year: 2024, Volume and Issue: unknown

Published: June 14, 2024

Abstract Aqueous batteries employing Zinc metal anodes (ZMAs) are considered to be promising next‐generation energy storage systems. However, the severe interfacial side reactions and dendrite growth restrict practical application of ZMAs in aqueous electrolytes. Herein, a water‐insoluble dual‐ionic electrolyte additive yttrium 2,4,5‐trifluorophenylacetate (YTFPAA) is developed stabilize ZMAs. Notably, ethanol‐solvated TFPAA − can capture H + thus buffer decreased pH caused by hydrolysis Y 3+ . Furthermore, dynamically adsorb onto surface through reversible oxidation‐reduction reaction, effectively suppressing forming water‐poor interface, enhancing reversibility Zn 2+ deposition/stripping redistributing flux. These favorable effects combined with dynamic electrostatic shielding effect ultimately enable uniform dense deposition. As result, Zn/Zn cells assembled 0.25YTFPAA exhibit an impressive cycle life 2100 h at 0.5 mA cm −2 –0.25 mAh More importantly, V 2 O 5 /Zn full cell shows ultra‐long up 18000 cycles 5.0 A g −1 This work highlights rational design multifunctional ionic additives for stabilizing

Language: Английский

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Highly stable planted MXene auxiliary layer for high-performance zinc anode deposition regulation

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 496, P. 154345 - 154345

Published: July 27, 2024

Language: Английский

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Bidentate Coordination Enables Anions‐Regulated Solvation Structure for Advanced Aqueous Zinc Metal Batteries

Angewandte Chemie International Edition, Journal Year: 2024, Volume and Issue: unknown

Published: Sept. 24, 2024

Abstract Rechargeable aqueous Zn metal batteries (AZMBs) are attractive for stationary energy storage due to their low cost and high safety. However, practical application is hindered by the excessive use of zinc anodes poor high‐temperature performance, caused severe side reactions dendritic growth issues. Here, an electrolyte design strategy reported based on bidentate coordination 2+ solvent tailor solvation structure. The triethylene glycol (TEG) co‐solvent with two‐oxygen sites demonstrated facilitate formation anions‐involved shell, greatly reducing activity coordinated H 2 O molecules. sequential reduction OTF − anions TEG leads organic–inorganic bilayer SEI (hydrophobic organic layer ion conductivity inorganic layer), protecting from dendrite growth, thus ensuring unprecedented reversibility (99.95 % over 5000 cycles at 0.5 mA cm −2 ). More importantly, full cells Zn||V 5 exhibit a record‐high cumulative capacity (2552 mAh ) under lean condition (E/C ratio=15 μl −1 ), limited supply (N/P ratio=1.9) areal (3.0

Language: Английский

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