Core‐Shell Quantum Wires‐Supported Single‐Atom Fe Electrocatalysts for Efficient Overall Water Splitting DOI Open Access
Bolin Li,

Fulin Deng,

Hanlu Wang

et al.

Small, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 12, 2024

It is of great significance for the development hydrogen energy technology by exploring new-type and high-efficiency electrocatalysts (such as single atom catalysts (SACs)) water splitting. In this paper, combining interface engineering doping engineering, a unique iron (Fe)-doped carbon-coated nickel sulfide (Ni

Language: Английский

Breaking symmetry for better catalysis: insights into single-atom catalyst design DOI
Peng Cao,

Xueqin Mu,

Fanjiao Chen

et al.

Chemical Society Reviews, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

This review examines the strategies of symmetry breaking (charge/coordination/geometric) in single-atom catalysts to regulate active site electronic structures, greatly enhancing catalytic performance.

Language: Английский

Citations

1
Switching CO-to-Acetate Electroreduction on Cu Atomic Ensembles DOI Creative Commons
Libing Zhang, Jiaqi Feng,

R. N. Wang

et al.

Journal of the American Chemical Society, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 17, 2024

The electrocatalytic reaction pathway is highly dependent on the intrinsic structure of catalyst. CO2/CO electroreduction has recently emerged as a potential approach for obtaining C2+ products, but it challenging to achieve high selectivity single product. Herein, we develop Cu atomic ensemble that satisfies appropriate site distance and coordination environment required CO-to-acetate conversion, which shows outstanding overall performance with an acetate Faradaic efficiency 70.2% partial current density 225 mA cm–2 formation rate 2.1 mmol h–1 cm–2. Moreover, single-pass CO conversion 91% remarkable stability can be also obtained. Detailed experimental theoretical investigations confirm significant advantages ensembles in optimizing C–C coupling, stabilizing key ketene intermediate (*CCO), inhibiting *HOCCOH intermediate, switch reduction from ethanol/ethylene conventional metallic ensembles.

Language: Английский

Citations

6
Double loading of nickel phosphide surface for efficient hydrogen evolution reaction DOI
J.G. Wang,

Fuyu Tian,

Lei Zhang

et al.

Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 673, P. 284 - 290

Published: June 11, 2024

Language: Английский

Citations

5
Engrossing Structural Developments of Double Perovskites for Viable Energy Applications DOI Creative Commons

Mariyam Saniya,

Iqra Sadiq,

Saman Shaheen

et al.

Materials Today Catalysis, Journal Year: 2024, Volume and Issue: 7, P. 100067 - 100067

Published: Oct. 9, 2024

Language: Английский

Citations

5
Metal–organic frameworks and their derivatives for the electrochemical CO2 reduction reaction: insights from molecular engineering DOI Creative Commons
Xiaoming Liu, Xuan‐He Liu, Xiangrui Zhang

et al.

Journal of Materials Chemistry A, Journal Year: 2024, Volume and Issue: 12(32), P. 20578 - 20605

Published: Jan. 1, 2024

Molecular engineering of MOF-based electrocatalysts for the CO 2 RR, computational simulations, and advanced characterization studies are discussed summarized to illustrate correlation between their structure performance.

Language: Английский

Citations

4
Nanozymes with Modulable Inhibition Transfer Pathways for Thiol and Cell Identification DOI
Lijun Hu, Lei Jiao, Chengjie Chen

et al.

Analytical Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 13, 2025

The elementary mechanism and site studies of nanozyme-based inhibition reactions are ambiguous urgently require advanced nanozymes as mediators to elucidate the effect. To this end, we develop a class featuring single Cu–N catalytic configurations B–O sites binding on porous nitrogen-doped carbon substrate (B6/CuSA) for inducing modulable transfer at atomic level. full redistribution electrons across sites, induced by incorporation, yields B6/CuSA with enhanced peroxidase-like activity versus CuSA. More importantly, CuSA features in cysteine expresses competitive through coordination bonds, an constant 0.048 mM. Benefiting from way nanozymes, possesses mixed approaches noncovalent bonds delivers record-mixed interaction 0.054 mM noncompetitive 0.71 Based CuSA, multichannel sensor array accomplishes detection various cancer cells, normal thiols. design principle work is endowed guidelines preliminary evaluation massive potential thiols, cell discrimination, disease prediction.

Language: Английский

Citations

0
Electron delocalization engineering via hierarchical modulation in single-atom catalysts for highly efficient electrochemical CO2 reduction DOI
Xu Han, Hong Liu, Pengfei Cao

et al.

Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 160634 - 160634

Published: Feb. 1, 2025

Language: Английский

Citations

0
A Review on Single Site Catalysts for Electrochemical CO2 Reduction DOI
Fan Yang, Haoyu Han,

Hailong Duan

et al.

Advanced Energy Materials, Journal Year: 2025, Volume and Issue: unknown

Published: March 18, 2025

Abstract Single site catalysts (SSCs), characterized by high atomic utilization and well‐defined active sites, exhibit significant potential in the field of CO 2 electroreduction (CO RR). Typically, SSCs tend to a 2‐electron transfer reaction RR, there remain challenges achieving efficient conversion above 2‐electrons (methane (CH 4 ) multicarbon products(C 2+ ). Therefore, systematic review is crucial summarize recent advancements single electrocatalysts their structure‐activity relationship. The discussion begins with state‐of‐the‐art characterization techniques SSCs. Then influence central atoms, coordination environments, support metal‐support interactions on catalytic performance discussed detail. Subsequently, regulation strategies improve activity selectivity CH C products are discussed. Furthermore, dynamic evolution metal sites true nature during RR also addressed. Finally, associated for product formation analyzed.

Language: Английский

Citations

0
Engineering the regulation strategy of active sites to explore the intrinsic mechanism over single‑atom catalysts in electrocatalysis DOI
Wen Jiang, Qiang Xiao, Weidong Zhu

et al.

Journal of Colloid and Interface Science, Journal Year: 2025, Volume and Issue: 693, P. 137595 - 137595

Published: April 14, 2025

Language: Английский

Citations

0
Enhanced CO2 Electroreduction by Stabilizing *COOH on Ni Single Atoms via Short‐ and Long‐Range Electronic Modulation DOI

Longlong Qi,

Haiyang Li, Shaochen Wang

et al.

Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown

Published: April 24, 2025

Abstract Ni single‐atoms (SAs) are active for electrocatalytic CO 2 reduction reaction (CO RR) to CO, but their performance still needs be further improved practical implementation. Herein, a strategy of “short‐ and long‐range modulation” is reported synergistically modulate the electronic structure SAs by constructing nanoparticles (NPs) integrated with N, P‐coordinated on N‐doped carbon supports (Ni‐P 1 N 3 /Ni NPs @NC). Experiments theoretical calculations reveal that both short‐range modulation involving Ni–P coordination collectively enhance electron localization around SAs, thus increasing binding strength key * COOH intermediate. This results in an RR lowering energy barrier. Ni‐P @NC exhibits Faradaic efficiency exceeding 99.0% across wide potential range from −0.5 −1.1 V versus reversible hydrogen electrode (vs RHE), highest partial current density −544 mA cm −2 at vs RHE.

Language: Английский

Citations

0