Carboxylation of Alkenes with CO2 via Photocatalytic Cleavage of C=C Double Bonds DOI
Qingyuan Meng, Pan‐Feng Yuan

Synlett, Journal Year: 2024, Volume and Issue: 35(17), P. 1937 - 1946

Published: May 14, 2024

Abstract The cleavage of double bonds in alkenes constitutes an integral process converting feedstock materials into high-value synthetic intermediates. Well-known examples such as the oxidative olefins and olefin metathesis only facilitate synthesis oxygen-containing compounds recombination olefins. Therefore, it is appealing to extend C=C bond yield more abundant transformations. Herein, we report a novel photocatalytic approach for deconstructive carboxylation with CO2 carboxylic acids absence transition metals. Compared reported carboxylations during which carbon numbers are typically increased, achieve exchange dioxide one carbons alkene bond, thus providing unchanged when terminal used.

Language: Английский

Tri‐site Synergistic Cu(I)/Cu(II)─N Single‐Atom Catalysts for Additive‐Free CO2 Conversion DOI

Qiuyan Cao,

Wenqiang Sun,

Zhihe Xiao

et al.

Small, Journal Year: 2024, Volume and Issue: 20(45)

Published: July 22, 2024

As the highly stable and abundant carbon source in nature, activation conversion of CO

Language: Английский

Citations

1
Carboxylation of Alkenes with CO2 via Photocatalytic Cleavage of C=C Double Bonds DOI
Qingyuan Meng, Pan‐Feng Yuan

Synlett, Journal Year: 2024, Volume and Issue: 35(17), P. 1937 - 1946

Published: May 14, 2024

Abstract The cleavage of double bonds in alkenes constitutes an integral process converting feedstock materials into high-value synthetic intermediates. Well-known examples such as the oxidative olefins and olefin metathesis only facilitate synthesis oxygen-containing compounds recombination olefins. Therefore, it is appealing to extend C=C bond yield more abundant transformations. Herein, we report a novel photocatalytic approach for deconstructive carboxylation with CO2 carboxylic acids absence transition metals. Compared reported carboxylations during which carbon numbers are typically increased, achieve exchange dioxide one carbons alkene bond, thus providing unchanged when terminal used.

Language: Английский

Citations

0