Angewandte Chemie,
Journal Year:
2024,
Volume and Issue:
136(40)
Published: July 1, 2024
Abstract
Two‐dimensional
(2D)
nanosheets‐based
membranes,
which
have
controlled
2D
nano‐confined
channels,
are
highly
desirable
for
molecular/ionic
sieving
and
confined
reactions.
However,
it
is
still
difficult
to
develop
an
efficient
method
prepare
large‐area
membranes
with
high
stability,
orientation,
accurately
adjustable
interlayer
spacing.
Here,
we
present
a
strategy
produce
metal
ion
cross‐linked
precisely
channels
stability
in
different
solutions
using
superspreading
shear‐flow‐induced
assembly
strategy.
For
example,
based
on
graphene
oxide
(GO)
exhibit
spacing
ranging
from
8.0±0.1
Å
10.3±0.2
Å,
precision
of
down
1
Å.
At
the
same
time,
value
orientation
order
parameter
(
f
)
GO
up
0.95
superb
solutions.
The
present,
can
be
generalized
preparation
variety
materials,
will
expand
application
scope
provide
better
performances
membranes.
Advanced Functional Materials,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Feb. 24, 2025
Abstract
Flexible
temperature
sensors
often
use
gels
to
achieve
skin‐inspired
softness,
but
the
water
evaporation
and
freezing
of
hydrogel
leakage
ionogel,
cause
unstable
signal
transmission
inaccurate
measurement
at
sub‐zero
temperatures.
Here
steady
hypothermic
sensing
is
achieved
by
designing
a
supramolecular
elastomer
containing
two
types
segments:
liquid‐free
iontronic
segment
transmit
electrical
charges
prevent
ion
leakage,
neutral
with
pendant
chains
damp
vibration
for
stable
transmission.
The
exhibits
excellent
tensile
properties,
adhesiveness,
self‐healing,
ionic
conductivity
A
wireless
system
fabricated
based
on
supermolecule
elastomer,
realizing
accurate,
steady,
sensitive
real‐time
detection.
Especially,
sensor
coefficient
resistance
(TCR)
8.87%
°C
−1
from
−20
−15
°C,
three
five
times
higher
than
that
most
flexible
sensors.
There
no
significant
difference
in
detected
this
an
infrared
thermal
imaging
camera.
Such
represents
step
toward
highly
accurate
cold
chain
transportation
beyond.
Nature Communications,
Journal Year:
2024,
Volume and Issue:
15(1)
Published: Nov. 15, 2024
Liquid
crystal
networks
(LCN)
have
attracted
surging
interest
as
extraordinary
energy-dissipation
materials
owning
to
their
unique
dissipation
mechanism
based
on
the
re-orientation
of
mesogens.
However,
how
integrate
high
Young's
modulus,
good
efficiency
and
wide
effective
damping
temperature
range
in
LCN
remains
a
challenge.
Here,
we
report
strategy
resolve
this
challenge
by
fabricating
robust
liquid
semi-interpenetrating
polymer
network
(LC-semi-IPN)
consisting
crystalline
LC
polymers
(c-LCP).
LC-semi-IPN
demonstrates
superior
synergistic
performance
both
mechanical
properties,
surpassing
all
currently
reported
LCNs.
The
crystallinity
c-LCP
endows
with
substantial
leap
modulus
(1800%
higher
than
single
network).
chain
reptation
also
promotes
an
enhanced
200%.
Moreover,
its
reaches
up
130
°C,
which
is
widest
for
By
leveraging
exceptional
performance,
can
be
further
utilized
functional
architected
structure
density
deformation-resistance.
design
energy
achieving
simultaneously
properties
challenging.
authors
fabricate
properties.
Angewandte Chemie International Edition,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Aug. 16, 2024
Two-dimensional
(2D)
nanosheets-based
membranes,
which
have
controlled
2D
nano-confined
channels,
are
highly
desirable
for
molecular/ionic
sieving
and
confined
reactions.
However,
it
is
still
difficult
to
develop
an
efficient
method
prepare
large-area
membranes
with
high
stability,
orientation,
accurately
adjustable
interlayer
spacing.
Here,
we
present
a
strategy
produce
metal
ion
cross-linked
precisely
channels
stability
in
different
solutions
using
superspreading
shear-flow-induced
assembly
strategy.
For
example,
based
on
graphene
oxide
(GO)
exhibit
spacing
ranging
from
8.0±0.1
Å
10.3±0.2
Å,
precision
of
down
1
Å.
At
the
same
time,
value
orientation
order
parameter
(f)
GO
up
0.95
superb
solutions.
The
present,
can
be
generalized
preparation
variety
materials,
will
expand
application
scope
provide
better
performances
membranes.
Science Advances,
Journal Year:
2025,
Volume and Issue:
11(15)
Published: April 9, 2025
Unpreferable
vibrations
and
impacts
pose
substantial
risks
to
sensitive
devices,
structures,
the
human
body,
demanding
materials
capable
of
providing
both
high
energy
dissipation
impact
protection
across
a
broad
temperature
range.
Traditional
damping
often
fail
meet
these
demands
because
trade-off
between
mechanical
strength.
We
introduce
an
innovative
strategy
fabricate
armored
polymer-fluid
gels
(APFGs)
that
combine
modulus
for
effective
under
extreme
conditions.
By
using
controlled
surface
cross-linking
process
through
diffusion,
we
greatly
enhance
strength
without
sacrificing
their
capabilities.
This
asymmetric
design
results
in
unprecedented
loss
factor
(tanδ
>
0.5
from
−45
degrees
135
Celsius,
peaking
at
tanδ
=
2.2)
while
achieving
tensile
20
megapascals.
method
resolves
long-standing
damping-modulus
trade-off,
positioning
APFGs
as
promising
candidates
robust
electronics
motion
applications.
Nature Communications,
Journal Year:
2025,
Volume and Issue:
16(1)
Published: May 12, 2025
Entanglement
significantly
enhances
the
mechanical
performance
and
functionality
of
both
natural
synthetic
materials.
However,
developing
straightforward,
versatile
strategies
for
creating
high-performance
entangled
polymer
materials
remains
a
challenge.
Here,
co-initiating-system
dual-mechanism
strategy
is
designed
fabricating
printable
multinetworks.
This
thermal-light
dual-initiation
process
benefits
synthesis
high-molecular-weight
polymers
promotes
rapid
formation
multinetworks
within
hydrogels.
The
resulting
long
chains
enable
hydrogels
with
higher
performance,
lower
stress
relaxation,
activation
energy
compared
to
short
chain-contained
samples.
Such
method
proves
more
effective
than
traditional
self-thickening
strengthening
techniques
enhancing
hydrogel
entanglements
also
compatible
additive
manufacturing,
enabling
design
complex
2D
webs
adaptive
capable
detecting
sensing
applications.
work
provides
an
designing
materials,
which
are
set
impact
numerous
fields,
from
advanced
material
science
beyond.
Macromolecular Rapid Communications,
Journal Year:
2025,
Volume and Issue:
unknown
Published: May 23, 2025
Abstract
Flexible
and
stretchable
conductive
elastomers
have
broad
application
prospects
in
health
monitoring,
wearable
flexible
sensor,
information
encryption.
However,
the
current
electronic
conductors
fillers
easily
fall
off,
performance
is
unstable,
other
problems
limit
their
practical
applications.
Therefore,
developing
a
elastomer
that
combines
high
mechanical
properties,
good
compatibility
of
filler
with
substrate,
stable
conductivity
remains
significant
challenge.
In
this
thesis,
self‐healing
excellent
conductivity,
substrate
successfully
synthesized
by
introducing
high‐density
hydrogen
bonding
dynamic
disulfide
into
polyurethane
network
addition
high‐performance
filler,
carbon
black
(Super
P).
It
possesses
8.4
×
10
−4
S
cm
−1
at
room
temperature,
tensile
strength
27.5
MPa,
an
elongation
break
578.7%,
as
well
resilience
46%
efficiency.
Wearable
strain
sensors,
designed
for
durability,
stability,
sensitivity,
are
ideal
detecting
human
motion,
monitoring
rehabilitation
training,
enabling
encrypted
transmission.
This
study
provides
new
ideas
high‐performance,
self‐repairable,
recyclable
materials,
which
promotes
development
devices.
Advanced Materials,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Nov. 14, 2024
Abstract
The
significant
modulus
difference
between
a
metal
coating
and
polymer
substrate
leads
to
interface
mismatches,
seriously
affecting
the
stability
of
flexible
devices.
Therefore,
enhancing
adhesion
layer
on
an
inert
prevent
delamination
becomes
key
challenge.
Herein,
ultrathin
protein
nanofilm
(UPN),
synthesized
by
disulfide‐bond‐reducing
aggregation,
is
proposed
as
strong
adhesive
enhance
coating.
Unlike
traditional
biopolymer
adhesives
with
micrometer‐scale
thicknesses,
UPN
minimized
nanometer/single‐molecular
scale.
Such
thereby
effectively
enhances
interfacial
strength
reduces
cohesion
contribution
in
entire
system
directly
connecting
two
interfaces
nearly
single‐molecular
thickness.
Using
layer,
multifunctional
could
be
reliably
adhered
substrates
ion
sputtering,
delivering
unprecedented
even
under
repetitive
mechanical
deformation.
Applications
this
design
include
reversible
transparency
control,
tension‐responsive
encryption,
reusable
optical
sensing,
wearable
capacitive
touch
sensors.
This
work
highlights
UPN's
potential
create
bonding
polymers
coatings,
offering
biocompatible
solution
high
surface
activity
low
cohesion,
facilitating
development
hybrid
devices
stable
nano‐coating.
