Science China Chemistry, Journal Year: 2025, Volume and Issue: unknown
Published: March 5, 2025
Language: Английский
Science China Chemistry, Journal Year: 2025, Volume and Issue: unknown
Published: March 5, 2025
Language: Английский
Materials Today Catalysis, Journal Year: 2025, Volume and Issue: unknown, P. 100092 - 100092
Published: Feb. 1, 2025
Language: Английский
Citations
0ACS ES&T Engineering, Journal Year: 2025, Volume and Issue: unknown
Published: Feb. 24, 2025
Language: Английский
Citations
0Advanced Materials, Journal Year: 2025, Volume and Issue: unknown
Published: Feb. 25, 2025
Abstract Electrochemically converting carbon dioxide (CO 2 ) and nitrate (NO 3 − into urea via the C─N coupling route offers a sustainable alternative to traditional industrial production technology, but it is still limited by poor yield rate, low Faradaic efficiency, insufficient kinetics. Herein, high‐density Ga─Y dual‐atom catalyst developed with loading up 14.1 wt.% of Ga Y supported on N, P‐co‐doped substrate (Ga/Y‐CNP) for electrosynthesis. The facilitates efficient through co‐reduction CO NO , resulting in high rate 41.9 mmol h −1 g efficiency 22.1% at −1.4 V versus reversible hydrogen electrode. In situ spectroscopy theoretical calculations reveal that superior performance attributed cross‐tuning between adjacent pair sites, which can mutually optimize their electronic states facilitating reduction *CO sites promoting conversion hydroxylamine (*NH OH) followed spontaneous *NH OH intermediates form bonds. This work pioneering strategy manipulate pathways active produce high‐value‐added chemicals.
Language: Английский
Citations
0Applied Catalysis O Open, Journal Year: 2025, Volume and Issue: unknown, P. 207036 - 207036
Published: March 1, 2025
Language: Английский
Citations
0Science China Chemistry, Journal Year: 2025, Volume and Issue: unknown
Published: March 5, 2025
Language: Английский
Citations
0