Advances of solid polymer electrolytes with high-voltage stability DOI Creative Commons

Zishao Zhao,

Weizhong Liang,

Shan Su

et al.

Next Materials, Journal Year: 2024, Volume and Issue: 7, P. 100364 - 100364

Published: Aug. 31, 2024

Language: Английский

Advanced Crosslinked Solid Polymer Electrolytes: Molecular Architecture, Strategies, and Future Perspectives DOI

Xiaoyue Zeng,

Xuewei Liu,

Huirong Zhu

et al.

Advanced Energy Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Sept. 17, 2024

Abstract Solid‐state batteries (SSBs) have attracted much attention for high‐energy‐density and high‐safety energy storage devices. Solid polymer electrolytes (SPEs) emerged as a critical component in the advancement of SSBs, owing to compelling advantages strong molecular structure‐designability, low cost, easy manufacturing, no liquid leakage. However, linear SPEs usually room‐temperature ionic conductivity due crystallization, melting at high temperature. Thus, crosslinked been proposed that chemical bonding between internal molecule chains can maintain solid state expand operational temperature, disrupt regularity segment, diminish crystalline degree, leading an enhancement conductivity. Furthermore, integration functional groups within SPE network significantly augment electrochemical performance SPEs. Herein, according structure, are categorized into four types: simple network, AB polymers (ABCP), semi‐interpenetrating (semi‐IPN), interpenetrating (IPN), then structure features disadvantages commonly used these types reviewed. In addition, with self‐healing, flame‐retardant, degradable, recyclability introduced. Finally, challenges prospects summarized, hoping provide guidance design future.

Language: Английский

Citations

11
Leveraging polymer architecture design with acylamino functionalization for electrolytes to enable highly durable lithium metal batteries DOI
Jiayu Zheng,

Lingyan Duan,

Hang Ma

et al.

Energy & Environmental Science, Journal Year: 2024, Volume and Issue: 17(18), P. 6739 - 6754

Published: Jan. 1, 2024

A novel polymer architecture design for GPEs is proposed via in situ copolymerization of VC and a new acylamino-crosslinker. This enables accelerated Li + transport dual-reinforced stable interfaces, contributing to long-lifespan LMBs.

Language: Английский

Citations

5
Designing Isocyanate‐Containing Elastomeric Electrolytes for Antioxidative Interphases in 4.7 V Solid‐State Lithium Metal Batteries DOI Open Access

Seong-Min Kim,

Michael J. Lee, Seung Ho Kwon

et al.

Advanced Energy Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Oct. 9, 2024

Abstract To facilitate the use of solid polymer electrolytes (SPEs) with high‐nickel (Ni) cathodes in high‐voltage lithium (Li) metal batteries (LMBs), it is crucial to address challenges low oxidative stability and formation vulnerable interphases. In this study, isocyanate groups (−N═C═O) are incorporated develop an SPE a bi‐continuous structure, consisting elastomeric plastic crystal phases. This rationally designed exhibits high ionic conductivity (0.9 × 10 −3 S cm −1 at 25 °C), excellent elasticity (elongation break 330%), enhanced (over 4.8 V vs. Li/Li⁺). A full cell, incorporating thin Li foil 40 µm, high‐Ni LiNi 0.8 Co 0.1 Mn O 2 (NCM811) cathode operating 4.7 Li/Li⁺, demonstrates cyclability, retaining 70% its initial capacity after 200 cycles under C‐rate 1C °C. The extended cycling isocyanate‐containing Li/Li⁺ attributed robust compact inorganic‐rich interphases enabled by antioxidative −N−C═O components, as well uniform deposition structured SPE. study suggests that system promising candidate for solid‐state LMBs constructing stable

Language: Английский

Citations

4
Non-flammable, conductive, and stretchable organic-ionogel for solid-state polymer lithium metal batteries DOI
Yanan Li, Tingting Xiao, Shunchao Ma

et al.

Journal of Energy Storage, Journal Year: 2025, Volume and Issue: 123, P. 116762 - 116762

Published: April 25, 2025

Language: Английский

Citations

0
Upcycling Spent Poly(ethylene oxide) Electrolytes into High-Value-Added Lithium Fluoride Nanowhiskers DOI
K. Yue, Shihui Zou, Jiaao Wang

et al.

ACS Applied Materials & Interfaces, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 25, 2025

All-solid-state batteries (ASSBs) represent a transformative advancement in energy storage, distinguished by their superior safety and density. However, the sustainable development of ASSBs depends critically on effective recycling solid electrolytes electrode materials from spent batteries, which poses significant challenges. Here, we present facile high-value-added carbothermal strategy for poly(ethylene oxide) (PEO)-based electrolytes. This approach enables direct synthesis one-dimensional lithium fluoride nanowhiskers (1D-LiF) utilizing PEO-based surface dead Li components. Through systematic investigation, identify two mechanisms growth 1D-LiF demonstrate high value these 1D LiF developing advanced composite simple efficient upcycling serves as valuable reference other solid-state supports ASSBs. The metal-catalysis-free also provides an instructive method rational metal halide nanomaterials.

Language: Английский

Citations

0
Elastomeric Polymer Network Electrolyte: Synthesis, Properties, and Applications DOI
Jinseok Park,

Heewoon Shin,

Wonho Lee

et al.

Progress in Polymer Science, Journal Year: 2025, Volume and Issue: unknown, P. 101944 - 101944

Published: March 1, 2025

Language: Английский

Citations

0
Fluorine-, Nitrogen-, and Boron-Functionalized Polymer Electrolytes for Advanced Lithium Metal Batteries DOI
Jinseok Park, Dongkyu Lee, Saehun Kim

et al.

ACS Nano, Journal Year: 2025, Volume and Issue: unknown

Published: April 16, 2025

Polymer electrolytes (PEs) have emerged as alternatives to conventional liquid in lithium metal batteries (LMBs) by addressing critical safety and performance challenges, including flame hazards, dendrite growth, interfacial instability. While oxygen-based PEs, such poly(ethylene oxide), been widely investigated, their limited ionic conductivity susceptibility electrochemical degradation under high-voltage operation prompted the exploration of heteroatom-functionalized PEs. Incorporating heteroatoms significantly enhances ion transport, stability, mechanical properties─all factors for robust reliable LMB performance. This review focuses on fluorine-, nitrogen-, boron-functionalized highlighting distinctive features design strategies applications. Recent developments key principles are summarized context high-performance PEs safer more LMBs advanced energy storage

Language: Английский

Citations

0
Janus Solid Electrolyte with Ionic and Electronic Dual Conductive Face Guiding Lithium Deposition Oriental To Connect with Lithium Metal Anode DOI

Xiaohua Qi,

Yihang Li, Shichen Zhang

et al.

ACS Energy Letters, Journal Year: 2025, Volume and Issue: unknown, P. 2679 - 2688

Published: May 9, 2025

Language: Английский

Citations

0
Design of Robust and Recyclable Covalent Elastomeric Networks through Dynamic Enamine–Urea Bonds DOI
Silong Chen,

Jian Ding,

Youlong Zhao

et al.

Macromolecules, Journal Year: 2024, Volume and Issue: unknown

Published: Sept. 4, 2024

Language: Английский

Citations

2
Advances of solid polymer electrolytes with high-voltage stability DOI Creative Commons

Zishao Zhao,

Weizhong Liang,

Shan Su

et al.

Next Materials, Journal Year: 2024, Volume and Issue: 7, P. 100364 - 100364

Published: Aug. 31, 2024

Language: Английский

Citations

1