Unraveling the Local Coordination Effect of Cu-N-C Single-Atom Catalyst towards CO Adsorption via Gas-Phase Cluster Model Approach DOI Creative Commons
Qing Wang, Dingding Lv, Jian Zhou

et al.

Chemical Science, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

To study M–N–C SACs at the atomic level, we propose a “splitting and decoupling” strategy. Gas-phase experiments reveal how varied coordination environments regulate CO adsorption on Cu center, guiding catalytic selectivity design.

Language: Английский

Confinement Synthesis of Atomic Copper‐Anchored Polymeric Carbon Nitride in Crystalline UiO‐66‐NH2 for High‐Performance CO2‐to‐CH3OH Photocatalysis DOI Open Access

Xingbing Liu,

Changyan Zhu,

Mengying Li

et al.

Angewandte Chemie International Edition, Journal Year: 2024, Volume and Issue: 63(45)

Published: July 29, 2024

Photocatalytic CO

Language: Английский

Citations

11
Porphyrin‐Based Covalent Organic Frameworks for CO2 Photo/Electro‐Reduction DOI Open Access

Sun Tingting,

Zhi Wang, Yuhui Wang

et al.

Angewandte Chemie International Edition, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 9, 2025

Photo/electro-catalytic CO2 reduction into high-value products are promising strategies for addressing both environmental problems and energy crisis. Duo to their advantageous visible light absorption ability, adjustable optic/electronic properties, definite active center, post-modification capability, excellent stability, porphyrin-based covalent organic frameworks (COFs) have emerged as attractive photo/electro-catalysts towards reduction. In this review, the research progress of COFs photo/electro-catalytic is summarized including design principles, catalytic performance, reaction mechanism. addition, review also presents some challenges prospects application in reduction, laying base fundamental efforts.

Language: Английский

Citations

2
Cooperative Atomic Palladium Site and Island-Distributed S-Scheme Heterostructure for Photocatalytic C2H6 Production DOI
Yan Wu, Zhujie Li, Qingqing Chen

et al.

ACS Catalysis, Journal Year: 2025, Volume and Issue: unknown, P. 3558 - 3569

Published: Feb. 12, 2025

Language: Английский

Citations

2
Accompanying Bi Clusters as Charge Mediators Effectively Enhance Synergetic Redox of Bi2Sn2O7/ZnIn2S4 S‐Scheme Heterostructure Composites DOI Open Access
Xing Liu, Yu-Chen Su, Yudong Li

et al.

Small, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 5, 2025

Abstract Achieving synergistic oxidation and reduction represents a significant challenge in the field of photocatalysis. In this study, hydrothermal/in situ construction Bi atom clusters within 2 Sn O 7 /ZnIn S 4 (BSO/ZIS) heterostructures is reported. These exhibit self‐accelerating charge‐transfer mechanisms facilitated by internal electric fields bonding bridges, resulting highly efficient light absorption capabilities. X‐ray photoelectron spectroscopy (XPS) Kelvin probe force microscopy (KPFM), as well theoretical calculations, indicate that canonical induction promotion electrons holes lowers activation energy CHO* generation, allowing simultaneous CO toluene over catalyst, enhances proton‐coupling electron‐transfer processes, unique reaction mechanism. The reactant, Bi‐Bi (B‐BSO/ZIS) heterostructure achieves rate to 726.3 µmol g −1 h (99.9% selectivity) benzaldehyde 2362.0 (98.0% selectivity), which increases activity 14.6 5.7 times compared pristine ZnIn . This study underscores significance modulating photocatalytic pathway through strategic selection metal reactants, contributing rational design photocatalysts for enhanced adsorption stabilization *H.

Language: Английский

Citations

1
Recent advances of metal active sites in photocatalytic CO2 reduction DOI Creative Commons
Wa Gao, Haonan Li, Jianqiang Hu

et al.

Chemical Science, Journal Year: 2024, Volume and Issue: 15(35), P. 14081 - 14103

Published: Jan. 1, 2024

Photocatalytic CO

Language: Английский

Citations

9
Cu-MOF composited with facet-engineered bimetallic alloys for inducing photocatalytic conversion of CO2 to C2H4 DOI
Xiangyu Lu, Peng Wang,

Zhao‐Feng Qiu

et al.

Chemical Communications, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

MIL-101(Cr) composited with Pt/Pd nanoalloy exposing the {111} facet can photocatalytically convert CO 2 to C H 4 , while one {100} has no such capability, demonstrating importance of facets in photocatalytic reduction.

Language: Английский

Citations

1
Trinuclear copper cluster-based COF with a high content of Cu–N2 single-atom sites: A multivariate signal-amplified photoelectrochemical aptasensor for the sensitive detection of mycotoxins DOI
Zhenzhen Li, Yifei Wang, Maura Pellei

et al.

Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 159603 - 159603

Published: Jan. 1, 2025

Language: Английский

Citations

1
Cu-Doped 2D-Bi2MoO6 Nanoribbon/rGO Photocatalysts for Selective Ethanol Production by Photocatalytic CO2 Reduction DOI
Arindam Mandal, Kajari Kargupta

ACS Applied Nano Materials, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 6, 2025

Hydrothermally produced Cu-doped two-dimensional (2D) Bi2MoO6 nanoribbon/rGO composite is explored as the photocatalyst for selective reduction of CO2 to ethanol. In particular, role Cu doping rGO-supported on C2 product selectivity investigated. Long nanoribbon-type pristine 2D-Bi2MoO6, 2D-Bi2MoO6 nanoribbon/rGO, and that doped with varying weight percentages copper (Cu) are synthesized characterized by XRD, FTIR, UV–vis spectroscopy, photoluminescence X-ray photoelectron SEM, TEM, EDX, EIS, BET analyses. Among all photocatalysts, optimum 2 wt % exhibiting an enhanced absorption edge visible light at 730 nm, smallest band gap 2.02 eV, lowest rate electron–hole pair recombination, improved charge transport offers highest photocatalytic activity (133.10 μmol gcat.–1 h–1) 100% ethanol production. Absence either or rGO leads formation a mixture methanol separates photoexcited electrons holes establishes electron-rich interface rGO-Cu junction 2%Cu-doped photocatalyst, facilitating high adsorption. serves trap catch more electrons. Electrons from Mo Bi atoms (of Bi2MoO6) drawn C 2p rGO) 3d orbitals. enhances thickened electron cloud (drawn Bi) surface C(rGO)-Cu, which facilitates adsorption reduction. The Mo–C–Cu/Mo–O–Cu bridge formed upon effectively reduces distance photogenerated recombination stabilize intermediate radicals such ·CO transfer abundant tapping sites formation. 2% in yield production 2.26 times compared nanoribbon/rGO.

Language: Английский

Citations

1
Theoretical design of dual-site metallo-covalent organic frameworks for efficient CO2 photoreduction into C2H4 DOI

K.M Chen,

Ya Wang,

Yuqi Dong

et al.

Applied Catalysis B Environment and Energy, Journal Year: 2024, Volume and Issue: 365, P. 124933 - 124933

Published: Dec. 11, 2024

Language: Английский

Citations

6
Confinement Synthesis of Atomic Copper‐Anchored Polymeric Carbon Nitride in Crystalline UiO‐66‐NH2 for High‐Performance CO2‐to‐CH3OH Photocatalysis DOI

Xingbing Liu,

Changyan Zhu,

Mengying Li

et al.

Angewandte Chemie, Journal Year: 2024, Volume and Issue: 136(45)

Published: July 29, 2024

Abstract Photocatalytic CO 2 reduction to value‐added fuels displays an attractive scenario enhance energy supply and reduce global warming. We report herein the confinement synthesis of polymeric carbon nitride (PCN) incorporating with Cu single atoms (CuSAs) inside crystalline UiO‐66‐NH , which combines merits heterojunction photocatalysis single‐atom catalysis (SAC) achieve high‐performance ‐to‐CH 3 OH conversion. A series spectral studies formation CuSAs@PCN . Remarkably, ternary composite shows excellent photocatalytic turnover frequency 4.15 mmol ⋅ h −1 g for Theoretical experimental demonstrate doping CuSAs, as well type‐II heterojunction, are causal factors CH generation. The study provides new insights designing photocatalyst conversion at atomic scale.

Language: Английский

Citations

5