Favorable Moderate Adsorption of Polysulfide on FeNi3 Intermetallic Compound Accelerating Conversion Kinetics for Advanced Lithium–Sulfur Batteries DOI
Shujun Liu, Tong Guo, Jun Jiang

et al.

Small, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 26, 2024

Sluggish conversion kinetics of polysulfides during discharge and the severe shuttle effect significantly hinder practical application lithium-sulfur (Li-S) batteries. In this work, lattice engineering strategy Fe hybridization is employed to manipulate bulk phase spacing FeNi

Language: Английский

Upgrading of nitrate to hydrazine through cascading electrocatalytic ammonia production with controllable N-N coupling DOI Creative Commons
Shunhan Jia, Libing Zhang,

Hanle Liu

et al.

Nature Communications, Journal Year: 2024, Volume and Issue: 15(1)

Published: Oct. 3, 2024

Language: Английский

Citations

5
Trimetallic mesoporous PdCuRu for efficient formate electrosynthesis from polyethylene terephthalate recycling DOI

Yuting Li,

Huiqin Yao,

Lizhi Sun

et al.

Science China Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 3, 2025

Language: Английский

Citations

0
Amorphous-Crystalline Heterostructure in Electrocatalytic 2D Platinum Group Metals DOI
Soumen Dutta

Current Opinion in Electrochemistry, Journal Year: 2025, Volume and Issue: unknown, P. 101653 - 101653

Published: Jan. 1, 2025

Language: Английский

Citations

0
Cu–Sb Atomic Pair Site in Metal Halide Perovskite for CO2 Reduction to Methanol DOI

Yayun Pu,

Fan Yang, Haowen Wang

et al.

Inorganic Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 24, 2025

Electrochemical conversion of CO2 into methanol has received extensive attention in recent years since is an efficient energy carrier and industrial feedstock. However, the selectivity to remains unsatisfied. In this work, Sb-doped Cs3Cu2I5 first rationally developed for electrochemical reduction, achieving remarkable high methanol. UV–vis absorption, X-ray photoelectron spectroscopy (XPS), density functional theory (DFT) calculations show that Sb dopants narrow band gap enhance metal–ligand hybridization due introduction 5p orbitals, which accordingly charge transfer. addition, Cu–Sb pair Sb@Cs3Cu2I5 perovskite synergistically catalyzes conversion. The Cu sites serve absorption activation, while stabilize intermediate *OCH2 through Sb–O bond superior oxygen affinity. plasma-treated sample with electron-deficient exhibits best as 88.38%. This work provides new insight highly metal halide perovskite-based catalysts

Language: Английский

Citations

0
Highly Strained Interfaces and Phase Separation for Boosting Electrochemical Methanol Oxidation and Hydrogen Evolution DOI
Zhen He, Runtian Wang, Chengming Wang

et al.

ACS Applied Materials & Interfaces, Journal Year: 2025, Volume and Issue: 17(9), P. 14109 - 14118

Published: Feb. 24, 2025

Constructing multimetallic alloy heterostructures with the desired interface and phase separation is a promising method to optimize electrochemical properties of noble metal nanomaterials. Nevertheless, tailoring elemental distribution lattice structures such nanomaterials still poses major difficulties. In this study, Cu-PtNi nanowires coupling PtNi PtNiCu active sites are fabricated by seeded synthesis on Cu template. Owing oxophilic nature anti-CO poisoning capability facets, as-synthesized exhibit enhanced methanol oxidation reaction (MOR) performance (7.73 A mgPt–1), outperforming those alloy, commercial Pt/C catalysts. Theoretical calculations in conjunction operando infrared reflection absorption spectroscopy demonstrate that lattice-compressed Pt3Ni (111)–Pt3NiCu (100) stands out as highly efficient site, which promotes OH intermediate adsorption simultaneously weakens CO during MOR. addition, at 10 mA cm–2, also an impressively reduced overpotential 35.2 mV for hydrogen evolution (HER) under alkaline conditions. This work offers strategy boost electrocatalytic

Language: Английский

Citations

0
Oxygen‐Bridged Ga‐O‐PtPd Triple Sites Boost Methanol‐Assisted Rechargeable Zn‐Air Batteries Through Suppressing COads Generation DOI Open Access
Daowei Gao, Juan Chen,

Yanao Zhang

et al.

Advanced Energy Materials, Journal Year: 2025, Volume and Issue: unknown

Published: March 4, 2025

Abstract Constructing high‐efficiency platinum (Pt)‐based catalysts for methanol oxidation reaction (MOR) by suppressing the intermediate CO ads generation is strongly desired and remains a grand challenge. Herein, concept of holding O‐bridged triple sites documented to strengthen “non‐CO” pathway selectivity forming HCOO − species during MOR. The obtained Ga‐O‐PtPd via grafting single‐atomic Ga on PtPd nanosheets achieves high current density 3.05 mAcm −2 MOR, which 5.65 times higher than commercial Pt/C (0.54 ), as well remarkably stability poison resistance. diffuse reflectance infrared Fourier transform spectroscopy (CO‐DRIFTS) results reveal that present weak binding ability, reducing intermediate. In addition, Ga‐O‐PtPd‐based Zn‐methanol‐air batteries an excellent activity compared with catalysts.

Language: Английский

Citations

0
Advances in Novel Supported Pt‐Based Catalysts for Methanol Electrolysis DOI

Jiaojiao Li,

Fulin Yang, Ligang Feng

et al.

Advanced Sustainable Systems, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 23, 2025

Abstract Methanol electrolysis, coupling thermodynamically favorable methanol oxidation reaction (MOR) and hydrogen evolution (HER), is a promising strategy for energy‐saving generation as compared with traditional water splitting. Pt‐based catalysts are the best choice while intrinsic activity utilization of Pt should be increased due to its high cost. Supporting engineering effective in boosting catalytic effectiveness, some novel supports diverse support effects developed accelerate kinetics improve efficiency. Herein, comprehensive review recent advances electrocatalysts methanol‐assisted production provided. The mechanism electrolysis anode MOR cathode HER first outlined, respectively. Then, performance enhancement effects, including anchoring, electronic, synergistic, strain briefly discussed. Subsequently, clarified by supports, metal oxides, phosphides, selenides, tellurides, presented, promotion effect relevant challenges future perspectives concluded last section, where most attention paid metal‐supporting their understanding study.

Language: Английский

Citations

0
Strong p–d Orbital Hybridization in Atomically Ordered Intermetallic Pd3Bi Metallene Enables Energy-Efficient Simultaneous Electrosynthesis of a Nylon-6 Precursor and Glycolic Acid DOI
You Xu,

Jiangwei Xie,

Youwei Sheng

et al.

ACS Catalysis, Journal Year: 2025, Volume and Issue: unknown, P. 6606 - 6617

Published: April 8, 2025

Language: Английский

Citations

0
Pt–Cu Porous Metallic Aerogels for Ethanol Electrooxidation Reaction DOI
Zhe Zhang, Shan Duan, Yecan Pi

et al.

ACS Applied Energy Materials, Journal Year: 2025, Volume and Issue: unknown

Published: April 19, 2025

Language: Английский

Citations

0
Thiol‐Modulation‐Induced Mesoporous Nanosheets with an Alloy/Intermetallic Heterophase for Efficient Electrochemical Ethylene Glycol‐Assisted Water Splitting DOI Creative Commons

Fukai Feng,

Sumei Han,

Chaoqun Ma

et al.

Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown

Published: April 25, 2025

Abstract Ligand modification has been widely utilized to tune the coordination environment of active sites in noble metal‐based electrocatalysts enhance their catalytic activity and selectivity. However, ligand‐induced structure transition catalyst its effect on performance is not clear. In this study, a thiol strategy developed prepare sulfur‐capped mesoporous PtPbBi nanosheets (S‐PtPbBi MNSs) with an alloy/intermetallic compound heterophase inhomogeneous tensile strain (≈3%). The obtained S‐PtPbBi MNSs exhibit excellent electrocatalytic for ethylene glycol oxidation reaction (EGOR), achieving Faradic efficiency up 92% converting EG glycolic acid. EG‐assisted electrochemical water splitting, only require low cell voltage 0.60 V achieve current density 10 mA cm −2 . anion exchange membrane electrolyzer utilizing can drive 500 at 1.63 V, along exceptional stability 200 h. Density functional theory calculations reveal that facilitates adsorption reactants enhances electron transfer between key intermediate. This work provides deep insights into ligand modification‐induced construction novel catalysts creates new opportunities small molecule‐assisted splitting efficient production hydrogen.

Language: Английский

Citations

0