Applied Catalysis A General, Journal Year: 2024, Volume and Issue: unknown, P. 120084 - 120084
Published: Dec. 1, 2024
Language: Английский
Applied Catalysis A General, Journal Year: 2024, Volume and Issue: unknown, P. 120084 - 120084
Published: Dec. 1, 2024
Language: Английский
JACS Au, Journal Year: 2025, Volume and Issue: 5(2), P. 684 - 692
Published: Feb. 2, 2025
Herein, we report a scalable and mild strategy for the monofluoroalkylation of wide array Giese acceptors via visible-light-mediated photoredox catalysis in continuous flow. The use flow technology significantly enhances productivity scalability, whereas mildness conditions functional group tolerance are ensured by leveraging 4CzIPN, transition-metal-free organic photocatalyst. Structurally diverse secondary tertiary monofluoroalkyl radicals can thus be accessed from readily available α-monofluorocarboxylic acids. Given reaction conditions, this protocol is also amenable to late-stage functionalization biologically relevant molecules such as menthol, amantadine, bepotastine, estrone derivatives, rendering it suitable application drug discovery programs, which introduction fluorinated fragments highly sought after. This method was extended enable reductive multicomponent radical-polar crossover transformation rapidly increase complexity assembled architectures single synthetic operation.
Language: Английский
Citations
3Tetrahedron, Journal Year: 2025, Volume and Issue: unknown, P. 134651 - 134651
Published: April 1, 2025
Language: Английский
Citations
0Journal of The Electrochemical Society, Journal Year: 2025, Volume and Issue: 172(2), P. 027503 - 027503
Published: Jan. 29, 2025
In this work, RCN/WCNTs nanocomposites were synthesized using a one-step method and characterized SEM, XPS, FTIR. An electrochemical sensor capable of sensitive rapid detection BPA was developed by modifying on glassy carbon electrode. The exhibited excellent response to in 0.2 M PBS (pH 7.0) under optimal selection conditions. linear range the 0.01–43 μM, limit (S/N = 3) 0.0017 μM. addition, good immunity, stability reproducibility. And it applied real samples.
Language: Английский
Citations
0Applied Catalysis A General, Journal Year: 2024, Volume and Issue: unknown, P. 120084 - 120084
Published: Dec. 1, 2024
Language: Английский
Citations
1