Covalent Organic Frameworks with Constrained Palladium Nanoclusters Lock the Enol‐Keto Tautomerism Enhancing Hydrogen Peroxide Photosynthesis DOI
Jie Zhou, Jinyang Chen,

Na Li

et al.

Small, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 26, 2024

The production of hydrogen peroxide from natural seawater is green and sustainable. However, the efficiency photocatalytic low due to degradation poisoning photocatalysts by abundant ions in seawater. Precisely controlling structure enhance their corrosion resistance minimize impact external particles a challenging task. Here, novel molecular engineering strategy reported which confined Pd nanoclusters locked keto structures production. Both experimental theoretical findings reveals that nanoclusters, when within structure, not only bolster stability photocatalyst but also augment photogenerated charge carriers' separation transport. This dual enhancement significantly boosts performance for synthesis. One photocatalysts, TAPT-2KtTb COF, exhibits an impressive rate 2676.3 µmol g

Language: Английский

Covalent Organic Frameworks with Constrained Palladium Nanoclusters Lock the Enol‐Keto Tautomerism Enhancing Hydrogen Peroxide Photosynthesis DOI
Jie Zhou, Jinyang Chen,

Na Li

et al.

Small, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 26, 2024

The production of hydrogen peroxide from natural seawater is green and sustainable. However, the efficiency photocatalytic low due to degradation poisoning photocatalysts by abundant ions in seawater. Precisely controlling structure enhance their corrosion resistance minimize impact external particles a challenging task. Here, novel molecular engineering strategy reported which confined Pd nanoclusters locked keto structures production. Both experimental theoretical findings reveals that nanoclusters, when within structure, not only bolster stability photocatalyst but also augment photogenerated charge carriers' separation transport. This dual enhancement significantly boosts performance for synthesis. One photocatalysts, TAPT-2KtTb COF, exhibits an impressive rate 2676.3 µmol g

Language: Английский

Citations

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