Single-atom catalysis for oxygen reduction, what's next? DOI Creative Commons
Canhui Zhang, Xu Liu,

Hanxu Yao

et al.

Next Materials, Journal Year: 2024, Volume and Issue: 6, P. 100464 - 100464

Published: Dec. 28, 2024

Language: Английский

Triggered factors and structure-activity relationship in the dynamic reconstruction processing of MOF for the alkaline oxygen evolution reaction DOI
Qianglong Qi, Chengxu Zhang, Jue Hu

et al.

Coordination Chemistry Reviews, Journal Year: 2024, Volume and Issue: 522, P. 216235 - 216235

Published: Oct. 1, 2024

Language: Английский

Citations

12
Screening of two-dimensional conductive MOFs as OER catalysts assisted by machine learning DOI
Yuyang Liu, Jianping Sun,

Yuxin Chai

et al.

Journal of Materials Science, Journal Year: 2025, Volume and Issue: 60(6), P. 2863 - 2877

Published: Jan. 22, 2025

Language: Английский

Citations

1
Amine-functionalisation of Ni-DOBDC MOF for CO2 adsorption DOI

Putri Andini,

Irena Khatrin, Iman Abdullah

et al.

Inorganic Chemistry Communications, Journal Year: 2025, Volume and Issue: unknown, P. 114319 - 114319

Published: March 1, 2025

Language: Английский

Citations

1
Mechanism of coordinated anions regulating the photocatalytic performance of Cu(I) metal–organic frameworks DOI
Shixiong Li,

Xiu Wu,

Yuzheng Cao

et al.

Inorganic Chemistry Communications, Journal Year: 2025, Volume and Issue: unknown, P. 114321 - 114321

Published: March 1, 2025

Language: Английский

Citations

1
Tailoring Coordination Fields of Asymmetric MO5S1‐Type Metal–Organic Frameworks Catalysts for Accelerated Oxygen Evolution Reaction DOI

Tengjia Ni,

Xianbiao Hou,

Jian Zhou

et al.

Advanced Functional Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Sept. 27, 2024

Abstract Asymmetric coordination has emerged as a promising approach to enhance the oxygen evolution reaction (OER) activity, yet achieving controlled synthesis of asymmetric structures comprehensively understand structure‐activity relationship remains challenging. In this study, facile and effective symmetry‐breaking strategy is reported for tailoring MO 5 S 1 ‐type metal–organic frameworks (MOFs) catalyst, establishing correlation between sulfur (S)‐mediated electron rearrangement adsorption/desorption dynamics oxygen‐related intermediates in OER. Experimental theoretical calculations reveal that well‐designed structure can effectively lower d‐band center, optimizing adsorption behavior OH * significantly decreasing energy barrier rate‐determining step (OH → O ) with enhanced O–H bond cleavage process. The S‐NiFe‐MOF/CFP catalyst demonstrates remarkable OER performance an alkaline electrolyte environment. More importantly, self‐assembled anion exchange membrane water electrolysis cell showcases low voltage 1.84 V deliver current density A cm −2 , maintaining long‐term stability over 100 h. This study unveils precise employing S, highlighting critical role manipulating redistribution through promote catalytic activity develop advanced MOF‐based catalysts.

Language: Английский

Citations

4
Modulating eg Occupancy by A‐Site Vacancy to Boost Photocatalytic CO2 Reduction on Perovskite Oxides DOI Open Access
Yibo Gao, Miaomiao Zhang,

Zutao Fan

et al.

Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 16, 2025

Abstract For photocatalytic CO 2 reduction, traditional ABO 3 perovskite oxides have suffered from the natural surface covered by passivated AO layer, resulting in low activity. Herein, double Sr TiFeO 6 is used as a precursor and citric acid employed to selectively dissolve A‐site cation, obtaining v ‐Sr with abundant vacancies. Without using any co‐catalysts or sacrificial agents, achieves efficient photoreduction of CH 4 91% selectivity 43.17 µmol g −1 h yield, which almost five times that original . The results indicate removing can increase concentration oxygen vacancies significantly reduce exciton binding energy 0.61 0.32 eV, thereby enhancing charge transfer efficiency. Furthermore, adjust electronic structure, leading decrease e electrons occupancy on active B‐site. This shift reaction intermediates strong adsorption moderate adsorption. Specifically, barrier water oxidation reaction, rate‐determining step for overall greatly reduced. work provides vivid case modulating structure oxide through introducing defects

Language: Английский

Citations

0
Defect-rich Ce2(CO3)2O·H2O@Fc’ heterojunction enabled high-performance electrocatalytic alkaline seawater oxidation DOI

J J Zhu,

Yanji Bao,

Siqi Zhao

et al.

Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 160375 - 160375

Published: Feb. 1, 2025

Language: Английский

Citations

0
Ligand-Tuned Surface Reconstruction Promotes Oxygen Evolution DOI

Guiling Wu,

Qianlin Chen, Jinrong Min

et al.

Applied Catalysis B Environment and Energy, Journal Year: 2025, Volume and Issue: unknown, P. 125356 - 125356

Published: April 1, 2025

Language: Английский

Citations

0
Artificial intelligence for catalyst design and synthesis DOI
Longhai Zhang,

Qiming Bing,

Qin Huang

et al.

Matter, Journal Year: 2025, Volume and Issue: 8(5), P. 102138 - 102138

Published: May 1, 2025

Language: Английский

Citations

0
Advancing the understanding and prediction accuracy of molecular adsorption energy with artificial intelligence DOI
Wen Liu, Ning Xu, Zheng Li

et al.

Physical review. B./Physical review. B, Journal Year: 2025, Volume and Issue: 111(19)

Published: May 9, 2025

Language: Английский

Citations

0