Metal Ion Catalysis within Hard Carbon Synthesis and Electrode Interface Engineering for Sodium‐Ion Batteries DOI

Xiaoyue Ma,

Ping Zhang, Xin Feng

et al.

Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown

Published: May 5, 2025

Abstract Metallic residues in biomass‐derived hard carbons (HCs) are conventionally considered detrimental to Na + ions storage, recent breakthroughs reveal that controlled metal‐ion doping can substantially enhance electrochemical performance. Suitable metal is beneficial its overall Consequently, manipulating the microstructure of HCs at molecular level achieve adaptive with ions, thereby fostering smoother diffusion environments and increasing storage sites for crucial achieving exceptional sodium‐ion batteries (SIBs) This review delves into commercialization potential SIBs provides a comprehensive summary development trajectory ion‐catalyzed hydrocarbons (MICHCs), which encompasses synthesis methodologies, intricate relationship between position/content performance, underlying reaction mechanisms. Regarding catalytic mechanism this outlines interaction HCs, offering theoretical foundations practical guidance developing high‐performance sodium materials. By regulating content type one adjust physicochemical properties local improve MICHCs. Research on MICHCs not only advances related disciplines but also fosters technological innovation industrial upgrading. discusses future developments challenges facing key technologies burgeoning field.

Language: Английский

Recent Advances, Key Strategies, and Challenges in Fast‐Charging Hard Carbon Anodes for Sodium‐Ion Batteries DOI
Wenjie Deng, Hai Yang, Hanyu Huo

et al.

Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown

Published: April 14, 2025

Abstract Sodium‐ion batteries (SIBs) have gradually entered the application market after years of development. To enhance user experience and reduce waiting time, development fast‐charging SIBs has become an inevitable trend. However, hard carbon (HC) anode materials currently in use face significant challenges, such as capacity degradation sodium metal plating during fast‐charging. This paper explores entire process Na + migration from electrolyte to bulk phase HC examines factors influencing at each stage. It then summarizes key strategies for achieving SIBs, with a focus on optimization, surface coating, structural optimization. Finally, highlights main challenges future prospects developing anodes, offering valuable insights advancing technologies.

Language: Английский

Citations

0
Covalent Organic Nanosheets with a Tunable Electronic Structure to Achieve Unprecedented Stability and High‐Performance in Sodium‐Ion Batteries DOI Creative Commons
Minseop Lee,

Nakyeong Lee,

Gi Seung Kwon

et al.

Small, Journal Year: 2025, Volume and Issue: unknown

Published: April 30, 2025

Abstract This study develops a new type of fluorinated covalent organic nanosheets (CONs) as anode materials for sodium‐ion batteries by incorporating an electron‐withdrawing benzothiadiazole (BT) unit and F atom into the framework. These modifications lead to reduced bandgap electron density, generating strong permanent dipoles that increased Na + accessible sites within self‐assembled solid‐state structure. To elucidate effect these electronic changes, storage performance D/A‐CON‐10‐F is compared nonfluorinated D/A‐CON‐10. The density in weakens its interaction with , yet enhances ion charge carrier conductivities, leading improved electrochemical performance. Notably, exhibits reversible discharge capacity ≈637 mA h g −1 at 100 maintaining structural stability over 5000 cycles excellent rate capability. results demonstrate dipole engineering CONs effectively transport long‐term stability, offering promising strategy next‐generation battery anodes.

Language: Английский

Citations

0
Concurrent Multifactorial Engineering of Closed-Pore Hard Carbon Architectures with Optimized Crystallographic Spacing for Advanced Sodium Storage DOI
Mutai Bao,

Zongtao Qu,

Yao Dai

et al.

Published: Jan. 1, 2025

Language: Английский

Citations

0
Close pore engineering for biomass-derived hard carbon toward high-performance sodium-ion batteries DOI

Chaojie Ren,

Jie He,

Hanyu Xu

et al.

Electrochimica Acta, Journal Year: 2025, Volume and Issue: unknown, P. 145968 - 145968

Published: March 1, 2025

Language: Английский

Citations

0
Metal Ion Catalysis within Hard Carbon Synthesis and Electrode Interface Engineering for Sodium‐Ion Batteries DOI

Xiaoyue Ma,

Ping Zhang, Xin Feng

et al.

Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown

Published: May 5, 2025

Abstract Metallic residues in biomass‐derived hard carbons (HCs) are conventionally considered detrimental to Na + ions storage, recent breakthroughs reveal that controlled metal‐ion doping can substantially enhance electrochemical performance. Suitable metal is beneficial its overall Consequently, manipulating the microstructure of HCs at molecular level achieve adaptive with ions, thereby fostering smoother diffusion environments and increasing storage sites for crucial achieving exceptional sodium‐ion batteries (SIBs) This review delves into commercialization potential SIBs provides a comprehensive summary development trajectory ion‐catalyzed hydrocarbons (MICHCs), which encompasses synthesis methodologies, intricate relationship between position/content performance, underlying reaction mechanisms. Regarding catalytic mechanism this outlines interaction HCs, offering theoretical foundations practical guidance developing high‐performance sodium materials. By regulating content type one adjust physicochemical properties local improve MICHCs. Research on MICHCs not only advances related disciplines but also fosters technological innovation industrial upgrading. discusses future developments challenges facing key technologies burgeoning field.

Language: Английский

Citations

0