Dinickel-Catalyzed Asymmetric Allylic Alkylation of Cyclic Ketones with Allylic Amine Derivatives DOI
Manman Zhai, Jian Zhang, Zhong‐Lin Tao

et al.

Organic Letters, Journal Year: 2025, Volume and Issue: unknown

Published: March 3, 2025

A dinickel-catalyzed direct asymmetric allylic alkylation of benzocyclic ketones has been developed. This method enables the efficient transformation various α-alkyl benzocyclohexanones and benzocyclopentanones with sulfonamides, affording chiral bearing α-quaternary carbon stereocenters in high yields excellent enantioselectivities.

Language: Английский

Dinickel-Catalyzed Asymmetric Allylic Alkylation of Cyclic Ketones with Allylic Amine Derivatives DOI
Manman Zhai, Jian Zhang, Zhong‐Lin Tao

et al.

Organic Letters, Journal Year: 2025, Volume and Issue: unknown

Published: March 3, 2025

A dinickel-catalyzed direct asymmetric allylic alkylation of benzocyclic ketones has been developed. This method enables the efficient transformation various α-alkyl benzocyclohexanones and benzocyclopentanones with sulfonamides, affording chiral bearing α-quaternary carbon stereocenters in high yields excellent enantioselectivities.

Language: Английский

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