Advanced Science,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Dec. 5, 2024
Abstract
Structural
stability
of
metal–organic
framework
(MOF)
is
crucial
for
their
application,
and
thus
it
great
significance
to
construct
MOFs
with
controllable
structural
stability.
Herein,
a
strategy
based
on
adjusting
the
electronic
environment
ligands
regulate
structure
MOF
proposed.
Briefly,
novel
Zr‐MOF
(Zr‐TA)
hydroxyl
groups
synthesized.
The
are
esterified
obtain
ester
stronger
electronegativity,
which
can
weaken
strength
coordination
between
metal
ion
ligand,
thereby
regulating
Zr‐MOF.
Notably,
this
achieve
adjustment
by
adding
modifiers
at
appropriate
time.
In
work,
used
greatly
improving
binding
ability
collagen
fibers,
hydrothermal
crosslinked
fibers
enhanced
82.6%.
Surprisingly,
also
be
applied
other
application
fields
that
require
dynamic
changes
in
MOF.
It
will
open
up
new
pathway
controlling
performance
Advanced Energy Materials,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Jan. 7, 2025
Abstract
With
the
increasing
safety
concerns
and
consensus
on
sustainability,
aqueous
zinc‐ion
batteries
(AZIBs)
are
gaining
significant
attention
as
a
green
efficient
alternative
for
energy
storage
technologies.
However,
prolonged
persistent
chemical
dissolution
electrochemical
capacity
fading
of
one
dominant
vanadium
oxide
cathodes
has
long
posed
an
unavoidable
challenge.
Meanwhile,
mechanism
AZIBs
remains
controversial,
along
with
formation
parasitic
derived
cathode‐related
products
during
repeated
charge/discharge
procedure.
Herein,
this
review
expects
to
provide
comprehensive
analysis
fundamental
redox
reactions
in
oxide‐based
AZIBs,
particular
emphasis
nanostructure
features
their
evolution,
ionic
transference,
occupation,
elucidate
underlying
mechanisms
involved
system.
Furthermore,
several
effective
strategies,
including
cathode
modification
electrolyte
design
summarized.
Finally,
offers
potential
avenues
advancing
materials,
inorganic
colloids,
high‐entropy
electrolytes,
characterization,
thereby
contributing
continued
development
field.
ACS Nano,
Journal Year:
2025,
Volume and Issue:
unknown
Published: March 6, 2025
Zinc-ion
secondary
batteries
have
been
competitive
candidates
since
the
"post-lithium-ion"
era
for
grid-scale
energy
storage,
owing
to
their
plausible
security,
high
theoretical
capacity,
plentiful
resources,
and
environment
friendliness.
However,
many
encumbrances
like
notorious
parasitic
reactions
Zn
dendrite
growth
hinder
development
of
zinc-ion
remarkably.
Faced
with
these
challenges,
eutectic
electrolytes
aroused
notable
attention
by
virtue
feasible
synthesis
tunability.
This
review
discusses
definition
advanced
functionalities
in
detail
divides
them
into
nonaqueous,
aqueous,
solid-state
regard
state
component
electrolytes.
In
particular,
corresponding
chemistry
concerning
solvation
structure
regulation,
electric
double
layer
(EDL)
structure,
solid-electrolyte
interface
(SEI)
charge/ion
transport
mechanism
is
systematically
elucidated
a
deeper
understanding
Moreover,
remaining
limitations
further
are
discussed
electrolyte
design
extended
applications.
Advanced Functional Materials,
Journal Year:
2025,
Volume and Issue:
unknown
Published: March 5, 2025
Abstract
Electrocatalytic
water
splitting
has
emerged
as
a
key
method
for
large‐scale
production
of
green
hydrogen.
Constructing
efficient,
durable,
and
low‐cost
electrocatalysts
the
hydrogen
evolution
reaction
at
high
current
densities
is
prerequisite
practical
industrial
applications
splitting.
Recently,
non‐noble
metal‐based
self‐supporting
electrodes
have
been
explored
density
due
to
their
cost‐effective,
conductivity
metal
substrate,
robust
interfacial
binding
between
catalyst
strong
mechanical
stability.
In
this
review,
recently
reported
(Ni,
Fe,
Cu,
Co,
Ti,
Mo,
alloy)
electrode
applied
are
comprehensively
summarized,
classified,
discussed.
Five
fundamental
design
principles
such
intrinsic
activity,
abundant
active
sites,
fast
electron
transfer,
mass
transport,
stability
proposed
discussed
achieve
high‐performance
under
densities.
Furthermore,
various
modification
strategies
including
heteroatom
doping,
morphology
engineering,
interface
phase
strain
engineering
enhance
catalytic
activity
durability
electrode.
Finally,
challenges
prospects
designing
efficient
stable
in
future
This
comprehensive
overview
will
provide
valuable
insight
guidance
development
production.
