Cited by Electron Transport Chains Promote Selective Photocatalytic Conversion of CO<sub>2</sub> to Methanol

Breaking symmetry for better catalysis: insights into single-atom catalyst design DOI

Peng Cao,

Xueqin Mu,

Fanjiao Chen

et al.

Chemical Society Reviews, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

This review examines the strategies of symmetry breaking (charge/coordination/geometric) in single-atom catalysts to regulate active site electronic structures, greatly enhancing catalytic performance.

Language: Английский

Citations

Co and N para-doping modulates the electronic structure of CdIn2S4 to enhance CO2 adsorption, activation and photocatalytic reduction DOI

Yi Liu, Yujia Liu,

Zuofang Yao

et al.

Applied Catalysis B Environment and Energy, Journal Year: 2025, Volume and Issue: 371, P. 125275 - 125275

Published: March 18, 2025

Language: Английский

Citations

Modulating Defect Concentration of Boron Nitride Flowers for CO₂ Photoreduction DOI

Zhi Liu, Baker Rhimi, Zheyang Liu

et al.

Inorganic Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 11, 2025

The efficient conversion of carbon dioxide into high-value chemicals presents a promising strategy for achieving neutrality. Defects play critical role in numerous catalytic reactions. However, an excessive number defects can lead to electron trapping, deactivating the catalyst surface. Optimizing defect concentration is crucial significantly enhancing performance. In this work, two types flower-like BN-based photocatalysts composed nanofibers were synthesized by situ self-assembly and high-temperature calcination. photocatalyst with fewer (Vpoor-BNF) achieved CO2 reduction rate 2 times higher than that more (Vrich-BNF), CO yield 32 μmol g–1 h–1 86.9% selectivity. Importantly, mechanism enhanced activity over BN-like was investigated combination various advanced characterization. results show C doping causes deposition, creating trap photogenerated electrons affect photocatalytic activity. contrast, Vpoor-BNF has longer carrier lifetime better photoelectric properties, which are beneficial photoreduction reaction. addition, good stability confirmed cyclic experiment. This study effective approach synthesizing defect-controlled catalysts, development photocatalysts.

Language: Английский

Citations

Dipropyne‐Modified N‐Heterocyclic Carbene Stabilized Atomically Precise Copper(I) Nanocluster Catalysts for CO₂ Electroreduction DOI

Bao‐Liang Han, Lei Zhao,

Zhi‐Rui Yuan

et al.

Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 25, 2025

Abstract Atomically precise copper(I) nanoclusters with stable active sites are highly sought‐after catalysts for the electrocatalytic CO₂ reduction reaction (CO₂RR), providing an exceptional platform to elucidate structure–activity relationships. However, rational synthesis of robust copper as effective electrocatalysts and understanding relationship between a more realistic site its performance remain significant challenge due their inherent instability. Here, novel dipropyne‐modified NHC ligand is elaborately devised two atomically nanoclusters, [Cu 17 H 6 (NHC ) 4 (dppm) ] 3+ ( Cu17a Ph Cu17b ), both exhibiting distinct unique square orthobicupola Cu core J 28 , Johnson solid). The σ‐ π‐bonding ligands imparts ultrahigh stability while coordination pattern μ 7 ‐ η σ 1 : π 2 facilitates exposure neighboring atoms, generating accessible catalytic sites. Electrocatalytic CO experiments show that achieves highest Faradaic efficiency ethylene production among reported nanoclusters. tandem mechanism RR elucidated through combination theoretical calculations attenuated total reflection‐surface‐enhanced IR absorption spectroscopy (ATR‐SEIRAS). This work not only introduces synthesizing but also offers critical insights into molecular design principles catalysts.

Language: Английский

Citations

Hollow sphere CeO2@t-BiVO4/m-BiVO4 with synergistic heterojunction and heterophase junction for enhanced photocatalytic redox ability DOI

Rui Liang, Wei Bi,

Yandong Du

et al.

Journal of Rare Earths, Journal Year: 2025, Volume and Issue: unknown

Published: April 1, 2025

Language: Английский

Citations

Asymmetric Charge Distribution in Atomically Precise Metal Nanoclusters for Boosted CO2 Reduction Catalysis DOI

Yuanxin Du,

Pei Wang,

Yi Fang

et al.

ChemSusChem, Journal Year: 2024, Volume and Issue: unknown

Published: Oct. 30, 2024

Recently, atomically precise metal nanoclusters (NCs) have been widely applied in CO

Language: Английский

Citations

Electron Transport Chains Promote Selective Photocatalytic Conversion of CO₂ to Methanol DOI

Fu Tian,

Wenjuan Li,

Ruwen Chen

et al.

Inorganic Chemistry, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 31, 2024

The photocatalytic conversion of carbon dioxide (CO

Language: Английский

Citations