Controlling Chirality and Stability of Gold Nanoclusters by PNP Pincer Ligand Diastereomers DOI
Chi‐Yun Lin, Xueling Lei, Ying Zhang

et al.

Nano Letters, Journal Year: 2025, Volume and Issue: unknown

Published: June 4, 2025

The emerging metal nanoclusters with atomically precise structures have gained considerable attention because they exhibit promising applications in various fields and serve as ideal models for studying the structure-property correlation of nanoparticles. Despite significant advances, it is still unclear how ligand diastereomers impact stability chirality nanoclusters. In this work, we systematically studied construction gold using PNP (PNP = 2,6-bis(1-(diphenylphosphaneyl)ethyl)pyridine) pincer consisting multiple stereoisomers. A metastable Au6 skeleton was found to be a key intermediate, which can controlled aspects by selectively produce Au9(R,R-PNP)4, Au9(S,S-PNP)4, Au9(R,S-PNP)4, Au6(R,S-PNP)2(R,R-PNP), Au6(R,S-PNP)2(S,S-PNP) intriguing properties such self-sorting spontaneous resolution. This work provides strategy regulating diastereomers.

Language: Английский

Hollow Giant Polyoxometalate Oxidation Shell Encapsulating Molecular Reduction Core for Unprecedented Photoredox Cascade Conversion DOI
Xiaohui Xie, Jingjing Liu, Jiao‐Min Lin

et al.

Published: Jan. 1, 2025

Language: Английский

Citations

0
Pincer-Ligand-Stabilized Group 10 Metal Nanoclusters: Chirality and Boat–Chair Structural Transformation DOI
Yan Zhao, Huanhuan Li, Ming Yao

et al.

The Journal of Physical Chemistry Letters, Journal Year: 2025, Volume and Issue: unknown, P. 2942 - 2949

Published: March 13, 2025

Atomically precise metal nanoclusters bridge the gap between atoms and nanoparticles, providing an ideal platform for correlating macroscopic properties of nanoparticles to their microstructures. In comparison rapid development coin nanoclusters, knowledge on group 10 is relatively limited because active nature, resulting in synthetic challenge. this work, we successfully synthesize three that is, Ni3(SNS)3, Ni3(SNOS)3, Pd3(SNS)3, by using SNS pincer ligands, which well-stabilize nickel palladium kernels. Intrinsic chirality originated from asymmetric arrangement surface ligands discovered. Oxidation-induced irreversible transformation boat-like Ni3(SNS)3 chair-like Ni3(SNOS)3 observed, boat/chair structure-dependent reactivity revealed. The structural features intriguing Ni3 Pd3 stabilized ligand will inspire further research nanoclusters.

Language: Английский

Citations

0
Hollow giant polyoxometalate oxidation shell encapsulating molecular reduction core for unprecedented photoredox cascade conversion DOI
Xiaohui Xie, Jingjing Liu, Jiao‐Min Lin

et al.

Chem, Journal Year: 2025, Volume and Issue: unknown, P. 102572 - 102572

Published: April 1, 2025

Language: Английский

Citations

0
Phosphine-induced conversion from Au36 to Au32 for constructing high-performance CO2RR catalyst DOI
Jian‐Sheng Ye,

Yali Dai,

Wenjun Liu

et al.

Dalton Transactions, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

A monophosphine-mediated structural modification strategy is performed to convert Au 36 into 32 nanoclusters and boost the eCO 2 RR performance.

Language: Английский

Citations

0
Controlling Chirality and Stability of Gold Nanoclusters by PNP Pincer Ligand Diastereomers DOI
Chi‐Yun Lin, Xueling Lei, Ying Zhang

et al.

Nano Letters, Journal Year: 2025, Volume and Issue: unknown

Published: June 4, 2025

The emerging metal nanoclusters with atomically precise structures have gained considerable attention because they exhibit promising applications in various fields and serve as ideal models for studying the structure-property correlation of nanoparticles. Despite significant advances, it is still unclear how ligand diastereomers impact stability chirality nanoclusters. In this work, we systematically studied construction gold using PNP (PNP = 2,6-bis(1-(diphenylphosphaneyl)ethyl)pyridine) pincer consisting multiple stereoisomers. A metastable Au6 skeleton was found to be a key intermediate, which can controlled aspects by selectively produce Au9(R,R-PNP)4, Au9(S,S-PNP)4, Au9(R,S-PNP)4, Au6(R,S-PNP)2(R,R-PNP), Au6(R,S-PNP)2(S,S-PNP) intriguing properties such self-sorting spontaneous resolution. This work provides strategy regulating diastereomers.

Language: Английский

Citations

0