Cited by Near-unity room-temperature phosphorescence quantum yield induced by halogen–halogen interaction in chiral hybrid copper(<scp>i</scp>) iodide clusters

Emission regulation in 0D hybrid copper halides via structural transformation: from defect to non-defect states for information encryption and storage DOI

Lin Yang, Xia Liu, Bohan Li

et al.

Chinese Chemical Letters, Journal Year: 2025, Volume and Issue: unknown, P. 110858 - 110858

Published: Jan. 1, 2025

Language: Английский

Citations

Luminescent Properties and Thermal Stability of [PPh4][Cu3I4] with a Unique Helical Structure DOI

Luyi Chen, Andrey A. Petrov, Mingming Li

et al.

Molecules, Journal Year: 2025, Volume and Issue: 30(3), P. 543 - 543

Published: Jan. 25, 2025

Hybrid halocuprates (I) with organic cations show great potential for optoelectronic applications due to their tunable luminescence and high thermal stability. In this study, the iodocuprate [PPh4][Cu3I4], featuring unique helical chains of face-sharing tetrahedra, was synthesized characterized. This compound exhibits a bandgap 3.1 eV orange at low temperature, attributed self-trapped exciton emission. [PPh4][Cu3I4] demonstrates exceptional stability among hybrid decomposition above 380 °C, forming stable melt ~255 °C without Cu+ oxidation in ambient atmosphere.

Language: Английский

Citations

Thermally Activated Delayed Fluorescence of Organic–Inorganic Hybrid Menshutkin-Type Cu–Sb Halides DOI

Yitong Lin,

Yang‐Peng Lin, Hao-Wei Lin

et al.

Inorganic Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 19, 2025

Organic-inorganic hybrid metal halides have attracted much attention due to their excellent optoelectronic properties. The heterometallic structure is expected achieve more complex luminescence centers, thereby improving the tunability of fluorescent materials. This paper reports synthesis crystals [Cu(2,2'-bpy)(PPh3)2][CuCl2(PPh3)2Sb2OCl4] (1, 2,2'-bpy = 2,2'-bipyridine, PPh3 triphenylphosphine) and (Mim)2[Sb2OCl6] (2, Mim 1-methylimidazole). Crystal 1 a new Menshutkin-type compound with double-layer hamburger-type structure, which characterized by main group (lone pair)···π (arene) supramolecular interactions. shows bright yellow light emission at room temperature has thermally activated delayed fluorescence (TADF) characteristic than twice increase PL intensity from 170 320 K. crystal arises charge transfer cation unit, as confirmed comparison study 2. Density functional theory (DFT) calculations further clarify that enhanced performance narrower bandgap are additional Cu(I) unit. good thermal stability air stability, ensuring its anti-counterfeiting application. work provides strategy for construction Cu-Sb compound.

Language: Английский

Citations

Novel Orange–Red Emissive Organic–Inorganic Hybrid Copper Halide for White Light-Emitting Diodes Application DOI

Lingling Xie,

Ning Lv,

Xuelu Wang

et al.

Optics Letters, Journal Year: 2025, Volume and Issue: 50(8), P. 2731 - 2731

Published: March 24, 2025

Organic–inorganic hybrid copper(I)-based metal halides (OIHCMHs) have emerged as promising alternatives to lead perovskites due their exceptional optical properties. However, the lack of low-energy light-emitting compounds prohibits further applications. Herein, we report an orange–red emissive (C 19 H 18 P) 2 Cu 4 Br 6 with a zero-dimensional structure. The photoluminescence (PL) peak locates at 640 nm PL quantum yield 69.3%, and large Stokes shift is 245 nm. Experimental analyses demonstrate bright broadband light emission derived from synergistic effect metal-to-ligand charge transfer or halide-to-ligand (MLCT/HLCT) excited state cluster-centered (CC) state. Furthermore, can be used phosphor for didoes (LEDs), by adding other blue- cyan-emitting phosphors, white LED high color rendering index over 94 achieved. This work not only demonstrates material design strategies preparing OIHCMHs but also inspires potential low-dimensional in quality

Language: Английский

Citations

Near-unity room-temperature phosphorescence quantum yield induced by halogen–halogen interaction in chiral hybrid copper(i) iodide clusters DOI

Y. Qin, Jianwu Wei, Jing Li

et al.

Inorganic Chemistry Frontiers, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

In this study, two pairs of 0D chiral copper iodide clusters were synthesized. The structural rigidity is increased by halogen modulation to obtain a near unity PLQY. applications in white LED and X-ray imaging are extremely promising.

Language: Английский

Citations