Molecular Design of Electron‐Rich Polyoxometalates Based Clusters Enabling Intelligent Energy Storage DOI Open Access
Chen Wang, Xiaozheng Duan, Jian Shen

et al.

Advanced Materials, Journal Year: 2025, Volume and Issue: unknown

Published: March 31, 2025

Abstract The fabrication of molecular cluster‐based intelligent energy storage systems remains a significant challenge due to the intricacies multifunctional integration at level. In this work, low‐valent metal atoms are successfully encapsulated within ɛ ‐type Keggin structures, yielding novel cluster denoted as CuMo 16 . This unique structure displayed characteristic “molybdenum red” coloration, with high degree reduction (76.47%), which played pivotal role in enhancing its electrochemical properties. specialized configuration significantly enhanced multi‐proton‐coupled electron transfer kinetics, enabling efficient and rapid release, up thirteen electrons per molecule. To construct an device, is employed proton‐coupled electron‐active material embedded polyvinyl alcohol (PVA) matrix, resulting flexible, wearable, rechargeable devices. flexible electronics not only demonstrate real‐time human motion detection but also exhibit remarkable performance, reaching peak capacity 194.19 mAh g −1 maintaining 68.2% retention after 2500 cycles. Molecular dynamics simulations reveal that integrating enhances performance electronics, regulation content provides effective strategy for optimizing electronic study lays foundation development systems.

Language: Английский

Molecular Design of Electron‐Rich Polyoxometalates Based Clusters Enabling Intelligent Energy Storage DOI Open Access
Chen Wang, Xiaozheng Duan, Jian Shen

et al.

Advanced Materials, Journal Year: 2025, Volume and Issue: unknown

Published: March 31, 2025

Abstract The fabrication of molecular cluster‐based intelligent energy storage systems remains a significant challenge due to the intricacies multifunctional integration at level. In this work, low‐valent metal atoms are successfully encapsulated within ɛ ‐type Keggin structures, yielding novel cluster denoted as CuMo 16 . This unique structure displayed characteristic “molybdenum red” coloration, with high degree reduction (76.47%), which played pivotal role in enhancing its electrochemical properties. specialized configuration significantly enhanced multi‐proton‐coupled electron transfer kinetics, enabling efficient and rapid release, up thirteen electrons per molecule. To construct an device, is employed proton‐coupled electron‐active material embedded polyvinyl alcohol (PVA) matrix, resulting flexible, wearable, rechargeable devices. flexible electronics not only demonstrate real‐time human motion detection but also exhibit remarkable performance, reaching peak capacity 194.19 mAh g −1 maintaining 68.2% retention after 2500 cycles. Molecular dynamics simulations reveal that integrating enhances performance electronics, regulation content provides effective strategy for optimizing electronic study lays foundation development systems.

Language: Английский

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