Electrochemically induced Meerwein arylation as a green strategy for the synthesis of arylbenzoquinone derivatives under batch and flow conditions
Abstract
An
electrochemical
Meerwein
arylation
reaction
was
reported
for
the
synthesis
of
aryl-benzoquinone
derivatives.
In
this
work,
efficient
derivatives
by
direct
electrolysis
aqueous
solution
containing
hydroquinone
and
aryldiazonium
salts
in
batch
a
homemade
continuous-flow
cells
is
reported.
system,
products
were
obtained
simple
undivided
cell
equipped
with
copper
anode
stainless
steel
cathode.
continuous
flow
simply
passing
salt
through
tube
made
rod
center.
All
equipment
required
both
types
from
common
commercial
sources.
This
protocol
green
cost-effective
due
to
use
electricity
performed
under
mild
safe
conditions
without
toxic
solvents
catalysts.
Research Square (Research Square), Journal Year: 2025, Volume and Issue: unknown
Published: April 10, 2025
Language: Английский