Electrode Development for Electro‐Organic Kolbe–Schmitt C–H Carboxylation of Benzene Using Cu Nanoparticles on Graphene Oxide Modified With MIL‐101 MOF for CO2 Capture in a DES Electrolyte System DOI

Zahra Behrouz,

Kambiz Banihashemi,

Mostafa Saadat

et al.

Applied Organometallic Chemistry, Journal Year: 2024, Volume and Issue: 39(1)

Published: Dec. 10, 2024

ABSTRACT This study focuses on developing an advanced electrode for the electro‐organic Kolbe–Schmitt C–H carboxylation of benzene. The uses copper (Cu) nanoparticles supported graphene oxide modified with MIL‐101 metal–organic framework (MOF). MOF enhances CO 2 capture, improving electrode's efficiency in a deep eutectic solvent (DES) system. reports high yields (89%–97%) synthesized benzoic acids 4(a–l) , facilitated by urea/ChCl as cost‐effective electrolyte, applying electric current 20 mA, h and at ambient temperature. innovative design facilitates efficient acid synthesis, while use accessible electrolyte reaction rate. were characterized through melting point analysis, 1 HNMR spectroscopy, CHN elemental composition. To assess properties, extensive characterization techniques such XPS, TGA, SEM, EDS, FT‐IR, BET surface area CV, FT‐IR used.

Language: Английский

Electrode Development for Electro‐Organic Kolbe–Schmitt C–H Carboxylation of Benzene Using Cu Nanoparticles on Graphene Oxide Modified With MIL‐101 MOF for CO2 Capture in a DES Electrolyte System DOI

Zahra Behrouz,

Kambiz Banihashemi,

Mostafa Saadat

et al.

Applied Organometallic Chemistry, Journal Year: 2024, Volume and Issue: 39(1)

Published: Dec. 10, 2024

ABSTRACT This study focuses on developing an advanced electrode for the electro‐organic Kolbe–Schmitt C–H carboxylation of benzene. The uses copper (Cu) nanoparticles supported graphene oxide modified with MIL‐101 metal–organic framework (MOF). MOF enhances CO 2 capture, improving electrode's efficiency in a deep eutectic solvent (DES) system. reports high yields (89%–97%) synthesized benzoic acids 4(a–l) , facilitated by urea/ChCl as cost‐effective electrolyte, applying electric current 20 mA, h and at ambient temperature. innovative design facilitates efficient acid synthesis, while use accessible electrolyte reaction rate. were characterized through melting point analysis, 1 HNMR spectroscopy, CHN elemental composition. To assess properties, extensive characterization techniques such XPS, TGA, SEM, EDS, FT‐IR, BET surface area CV, FT‐IR used.

Language: Английский

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