Modular reductive radical-polar crossover-based acyl migration reactions of N-vinylimides with alkyl, silyl, and acyl radicals DOI Creative Commons

Yutao Jing,

Li Zhang,

Li Qiu

et al.

RSC Advances, Journal Year: 2025, Volume and Issue: 15(15), P. 11582 - 11586

Published: Jan. 1, 2025

Generation of α-amino ketones: photocatalytic radical addition/acyl migration cascade processes were reported on reactions enamides with dihydroquinazolinones or acyl oxime acetates.

Language: Английский

A Radical Precursor Based on the Aromatization of p-Quinol Esters Enabled by Pyridine-Boryl Radical DOI
Xiaoli Huang,

Ruji Xiong,

Yi Cui

et al.

The Journal of Organic Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 13, 2025

A class of prearomatic carboxylic acid p-quinol ester radical precursors has been developed successfully, which could undergo homolytic cleavage the para C-O bond esters via pyridine-boryl radical-induced aromatization in presence pyridines and diboron reagents, affording corresponding alkyl decarboxylation from carboxyl situ. In addition, were further applied substitution with phenylsulfonyl compounds self-coulpings. This method not only provides a new approach to generation intermediate but also expands application boron radicals.

Language: Английский

Citations

0
Modular reductive radical-polar crossover-based acyl migration reactions of N-vinylimides with alkyl, silyl, and acyl radicals DOI Creative Commons

Yutao Jing,

Li Zhang,

Li Qiu

et al.

RSC Advances, Journal Year: 2025, Volume and Issue: 15(15), P. 11582 - 11586

Published: Jan. 1, 2025

Generation of α-amino ketones: photocatalytic radical addition/acyl migration cascade processes were reported on reactions enamides with dihydroquinazolinones or acyl oxime acetates.

Language: Английский

Citations

0