Photocatalytic Hydrogenation of Alkenes Using Water as Both the Reductant and the Proton Source DOI Creative Commons

Xinzhe Tian,

Ming Qiu, Wan‐Kai An

et al.

Advanced Science, Journal Year: 2024, Volume and Issue: 11(44)

Published: Oct. 9, 2024

Abstract Utilization of clean and low‐cost water as the reductant to enable hydrogenation alkenes is highly attractive in green chemistry. However, this research subject considerably challenging due sluggish kinetics oxidation half‐reaction. It also very difficult avoid undesired because that far easier occur than desired from thermodynamic standpoint. Herein, challenge overcome by applying a cooperative catalysis where HCl used cocatalyst accelerate Pt/g‐C 3 N 4 ‐catalyzed suppress alkene. This provides an example for using proton source photocatalytic alkenes. The present method exhibits broad substrate applicability, allows various arylethenes aliphatic undergo smoothly.

Language: Английский

Photocatalytic Hydrogenation of Alkenes Using Water as Both the Reductant and the Proton Source DOI Creative Commons

Xinzhe Tian,

Ming Qiu, Wan‐Kai An

et al.

Advanced Science, Journal Year: 2024, Volume and Issue: 11(44)

Published: Oct. 9, 2024

Abstract Utilization of clean and low‐cost water as the reductant to enable hydrogenation alkenes is highly attractive in green chemistry. However, this research subject considerably challenging due sluggish kinetics oxidation half‐reaction. It also very difficult avoid undesired because that far easier occur than desired from thermodynamic standpoint. Herein, challenge overcome by applying a cooperative catalysis where HCl used cocatalyst accelerate Pt/g‐C 3 N 4 ‐catalyzed suppress alkene. This provides an example for using proton source photocatalytic alkenes. The present method exhibits broad substrate applicability, allows various arylethenes aliphatic undergo smoothly.

Language: Английский

Citations

1