Efficient CH4 oxidation to C1/C2 oxygenates over cluster-dispersing Rh decorated ZSM-5
Xin Zhang,
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Chao Hu,
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Jingting Jin
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et al.
RSC Advances,
Journal Year:
2025,
Volume and Issue:
15(2), P. 1301 - 1310
Published: Jan. 1, 2025
Converting
methane
directly
into
liquid
oxygenated
products
such
as
methanol
and
acetic
acid
is
an
energy-efficient
method
with
significant
potential
for
various
industrial
applications.
Language: Английский
Orbital‐Driven Insights into Enantioselective Hydrofunctionalization of Alkenes Catalyzed by Co‐Salen Complexes: Study on Singlet and Triplet States
ChemPlusChem,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Oct. 10, 2024
The
Co(salen)
([LCo(II)])
mediated
hydrofunctionalization
of
alkenes
is
a
highly
significant
method
for
forming
enantioselective
products.
In
this
work,
we
conducted
comprehensive
computational
investigations
to
gain
insights
the
reaction
mechanism.
orbital
analysis
and
intrinsic
bond
(IBO)
were
utilized
unravel
flow
electrons
during
progress
reaction.
We
explored
various
spin
state
surfaces
understand
possible
pathways
Initially,
[LCo(II)]
reacts
with
an
oxidant
tertbutyl
peroxybenzoate,
yielding
[LCo(III)OC(O)Ph]
[LCo(III)O
Language: Английский