Electrochemically Preplated Lithium on Silver Nanoparticle‐Decorated Three‐Dimensional Vertically Aligned Graphene Foam for Rechargeable Lithium Batteries DOI Creative Commons

Hyun Jung Shin,

Sangbaek Park, Dong‐Wan Kim

et al.

International Journal of Energy Research, Journal Year: 2024, Volume and Issue: 2024(1)

Published: Jan. 1, 2024

Graphene‐based materials, which exhibit large surface areas and superior electrical properties, are promising materials as anodes in lithium‐ion batteries (LIBs). However, the formation of a solid electrolyte interphase (SEI) on surfaces these electrodes causes loss active lithium, leading to severe reduction coulombic efficiency cycle retention. In this study, we combined an electrochemical lithium deposition (ELD) strategy, wherein was inserted into electrode minimize during cycling, with use vertically aligned three‐dimensional (3D) graphene foam. This foam, created via freeze‐casting, facilitated uniform distribution ELD, enhancing utilization. Consequently, preplated foam anode could improve charge transfer stabilize SEI. It exhibited retention 86% at current density 0.5 C for 200 cycles LIBs, is that film‐type foils. Moreover, it enabled easy infiltration polymer through sheets while maintaining its original cell performance liquid electrolyte. Furthermore, higher discharge capacity than foil same negative/positive ratio high‐areal‐capacity lithium–sulfur batteries. Therefore, paper indicates potential high safety, various next‐generation rechargeable

Language: Английский

Uneven distribution of F improved electrochemical performances for regenerated LiNi1/3Co1/3Mn1/3O2 through simple heat treatment methods DOI
Lihua Wang,

Haobo Deng,

Yongzhi Chen

et al.

Surfaces and Interfaces, Journal Year: 2025, Volume and Issue: unknown, P. 106126 - 106126

Published: Feb. 1, 2025

Language: Английский

Citations

0

Li-Si alloy pre-lithiated silicon suboxide anode constructing a stable multiphase lithium silicate layer promoting Ion-transfer kinetics DOI
Yingying Shen, Yun Zheng, Jiangmin Jiang

et al.

Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 679, P. 855 - 867

Published: Oct. 9, 2024

Language: Английский

Citations

1

Nanocatalysis in Cathode Pre-lithiation for Lithium-ion Battery: Progress and Challenges DOI
Fujun Niu, Liang Qiu, Huai Chen

et al.

Nanoscale, Journal Year: 2024, Volume and Issue: 16(46), P. 21294 - 21308

Published: Jan. 1, 2024

This review focuses on nanocatalysis in cathode pre-lithiation, summarizes recent progress versatile nanocatalysts for efficient pre-lithiation additive decomposition and highlights future challenges directions commercialization.

Language: Английский

Citations

1

Electrochemically Preplated Lithium on Silver Nanoparticle‐Decorated Three‐Dimensional Vertically Aligned Graphene Foam for Rechargeable Lithium Batteries DOI Creative Commons

Hyun Jung Shin,

Sangbaek Park, Dong‐Wan Kim

et al.

International Journal of Energy Research, Journal Year: 2024, Volume and Issue: 2024(1)

Published: Jan. 1, 2024

Graphene‐based materials, which exhibit large surface areas and superior electrical properties, are promising materials as anodes in lithium‐ion batteries (LIBs). However, the formation of a solid electrolyte interphase (SEI) on surfaces these electrodes causes loss active lithium, leading to severe reduction coulombic efficiency cycle retention. In this study, we combined an electrochemical lithium deposition (ELD) strategy, wherein was inserted into electrode minimize during cycling, with use vertically aligned three‐dimensional (3D) graphene foam. This foam, created via freeze‐casting, facilitated uniform distribution ELD, enhancing utilization. Consequently, preplated foam anode could improve charge transfer stabilize SEI. It exhibited retention 86% at current density 0.5 C for 200 cycles LIBs, is that film‐type foils. Moreover, it enabled easy infiltration polymer through sheets while maintaining its original cell performance liquid electrolyte. Furthermore, higher discharge capacity than foil same negative/positive ratio high‐areal‐capacity lithium–sulfur batteries. Therefore, paper indicates potential high safety, various next‐generation rechargeable

Language: Английский

Citations

0