Electrophotocatalysis for Organic Synthesis
Chemical Reviews,
Journal Year:
2024,
Volume and Issue:
124(21), P. 12264 - 12304
Published: Oct. 23, 2024
Electrocatalysis
and
photocatalysis
have
been
the
focus
of
extensive
research
efforts
in
organic
synthesis
recent
decades,
these
powerful
strategies
provided
a
wealth
new
methods
to
construct
complex
molecules.
Despite
intense
efforts,
only
recently
has
there
significant
on
combined
use
two
modalities.
Nevertheless,
past
five
years
witnessed
rapidly
growing
interest
area
electrophotocatalysis.
This
hybrid
strategy
capitalizes
enormous
benefits
using
photons
as
reagents
while
also
employing
an
electric
potential
convenient
tunable
source
or
sink
electrons.
Research
this
topic
led
number
for
C-H
functionalization,
reductive
cross-coupling,
olefin
addition
among
others.
field
seen
broad
range
catalyst
types,
including
both
metal
organocatalysts.
Of
particular
note
work
with
open-shell
photocatalysts,
which
tend
comparatively
large
redox
potentials.
Electrochemistry
provides
means
generate
such
species,
making
electrophotocatalysis
particularly
amenable
intriguing
class
catalyst.
review
surveys
applied
synthesis,
organized
broadly
into
oxidative,
reductive,
neutral
transformations.
Language: Английский
A review of recent advances in electrochemical and photoelectrochemical late-stage functionalization classified by anodic oxidation, cathodic reduction, and paired electrolysis
Beilstein Journal of Organic Chemistry,
Journal Year:
2024,
Volume and Issue:
20, P. 2500 - 2566
Published: Oct. 9, 2024
With
the
resurgence
of
electrosynthesis
in
organic
chemistry,
there
is
a
significant
increase
number
routes
available
for
late-stage
functionalization
(LSF)
drugs.
Electrosynthetic
methods,
which
obviate
need
hazardous
chemical
oxidants
or
reductants,
offer
unprecedented
control
reactions
through
continuous
variation
applied
potential
and
possibility
combination
with
photochemical
processes.
This
capability
substantial
advantage
performing
electrochemical
photoelectrochemical
LSF.
Ultimately,
these
protocols
are
poised
to
become
vital
component
medicinal
chemist's
toolkit.
In
this
review,
we
discuss
that
have
been
demonstrated
be
applicable
LSF
pharmaceutical
drugs,
their
derivatives,
natural
substrates.
We
present
analyze
representative
examples
illustrate
electrochemistry
photoelectrochemistry
valuable
molecular
scaffolds.
Language: Английский
Applications of Electrophotocatalysis in C‐H Functionalization of Organic Molecules.
Chemistry - A European Journal,
Journal Year:
2024,
Volume and Issue:
30(57)
Published: July 6, 2024
Electrophotocatalysis
(EPC)
has
evolved
as
a
new
scientific
discipline
around
the
boundary
of
highly
active
fields:
electrochemistry
and
photocatalysis.
EPC
allows
us
to
combine
energy
light
electric
potential
activate
previously
inaccessible
compounds
via
single-electron
transfer
(SET).
Herein,
we
review
most
essential
applications
C-H
functionalization
molecules.
This
work
discusses
mechanisms
that
can
be
encountered
when
designing
such
processes
analyzes
technical
aspects
performing
reactions
in
laboratory.
Language: Английский
Throwing Light on Synthetic Molecular Photoelectrocatalysis (Part II): selected recent transformations of organic compounds and a future perspective in organic synthesis
Current Opinion in Electrochemistry,
Journal Year:
2025,
Volume and Issue:
unknown, P. 101674 - 101674
Published: Feb. 1, 2025
Language: Английский
Photoelectrocatalytic response of tris(2,2′-bipyridyl)ruthenium(II)-modified mesoporous silica film on ITO electrode with methyl viologen quencher and EDTA donor
Mahmoud Rahal,
No information about this author
Neus Vilà,
No information about this author
Christelle Despas
No information about this author
et al.
Journal of Solid State Electrochemistry,
Journal Year:
2025,
Volume and Issue:
unknown
Published: March 18, 2025
Language: Английский
Recent Progress in External‐field Enhanced Photo‐Electrochemistry
ChemSusChem,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Oct. 18, 2024
The
ever-growing
demands
for
energy
supply
have
put
great
stress
on
environment
protections.
Photo-electrochemistry
(PEC)
is
a
repaid
developing
technique
which
can
directly
transform
solar
into
chemical
compounds
and
been
regarded
as
promising
strategy
to
solve
the
environmental
problems.
However,
biggest
restriction
fast
recombination
of
photo-generated
charge
carriers
greatly
limits
PEC
efficiency.
In
recent
years,
introducing
external-field
system
proved
be
powerful
method
enhance
performance
attracted
more
attentions.
this
review,
we
summarized
remarkable
progresses
in
enhanced
reactions
including
mechanical
field,
thermal
electrical
magnetic
field
muti-field
coupling.
enhancing
principles
different
external-fields
also
systemically
discussed.
Furthermore,
challenges
outlook
are
presented.
Language: Английский