Tetranuclear N-Heterocyclic Carbene Palladium Acetate—The Fast-Initiating Precatalyst of Suzuki Coupling DOI Open Access
Sylwia Ostrowska, Szymon Rogalski, Maciej Kubicki

et al.

Catalysts, Journal Year: 2024, Volume and Issue: 14(11), P. 836 - 836

Published: Nov. 20, 2024

A tetranuclear N-heterocyclic palladium carbene acetate, characterised by a [Pd]/[NHC] = 2/1 ratio, was synthesised and shown to be catalytically active in Suzuki coupling. Single crystal XRD studies of the complex revealed its unprecedented geometry, with presence three coordinated centres. The catalytic activity is significantly higher than that analogues containing same ligand. Preliminary have been carried out determine properties complex.

Language: Английский

Palladium-catalyzed cross-coupling of arylcarboxylic acid 2-pyridyl esters with terminal alkynes DOI

Hang Yu,

Jingjing Nie,

Zhong‐Xia Wang

et al.

Organic & Biomolecular Chemistry, Journal Year: 2024, Volume and Issue: unknown

Published: Jan. 1, 2024

In the presence of Na

Language: Английский

Citations

0
Tetranuclear N-Heterocyclic Carbene Palladium Acetate—The Fast-Initiating Precatalyst of Suzuki Coupling DOI Open Access
Sylwia Ostrowska, Szymon Rogalski, Maciej Kubicki

et al.

Catalysts, Journal Year: 2024, Volume and Issue: 14(11), P. 836 - 836

Published: Nov. 20, 2024

A tetranuclear N-heterocyclic palladium carbene acetate, characterised by a [Pd]/[NHC] = 2/1 ratio, was synthesised and shown to be catalytically active in Suzuki coupling. Single crystal XRD studies of the complex revealed its unprecedented geometry, with presence three coordinated centres. The catalytic activity is significantly higher than that analogues containing same ligand. Preliminary have been carried out determine properties complex.

Language: Английский

Citations

0