Electrochemical Enantioselective Nickel‐Catalyzed Cross‐Coupling of Aldehydes with Aryl Iodides DOI Creative Commons

Liangjian Hu,

Jospin Le Blanc Lele Fosso,

Régis Guillot

et al.

Chemistry - A European Journal, Journal Year: 2024, Volume and Issue: unknown

Published: Oct. 4, 2024

The preparation of enantioenriched diarylmethanol derivatives is described using nickel-catalyzed electrochemical cross-couplings between various alkyl/aryl aldehydes and aryl iodides. Performed in an cell equipped with iron anode a nickel cathode, this electrocatalytic variant led to the scalemic targeted products presence 2,2-bis((4 R,5S)-4,5-diphenyl-4,5-dihydrooxazol-2-yl)acetonitrile (L2), as enantiopure cyano-bis(oxazoline) ligand. X-ray structure analysis pre-catalyst, for instance [Ni

Language: Английский

Nitro Substrates in Reductive Electrosynthesis: A Review DOI Creative Commons
Sebastián O. Simonetti, Sebastian B. Beil, Siegfried R. Waldvogel

et al.

ACS electrochemistry., Journal Year: 2025, Volume and Issue: unknown

Published: May 6, 2025

Language: Английский

Citations

0
Electrochemical Enantioselective Nickel‐Catalyzed Cross‐Coupling of Aldehydes with Aryl Iodides DOI Creative Commons

Liangjian Hu,

Jospin Le Blanc Lele Fosso,

Régis Guillot

et al.

Chemistry - A European Journal, Journal Year: 2024, Volume and Issue: unknown

Published: Oct. 4, 2024

The preparation of enantioenriched diarylmethanol derivatives is described using nickel-catalyzed electrochemical cross-couplings between various alkyl/aryl aldehydes and aryl iodides. Performed in an cell equipped with iron anode a nickel cathode, this electrocatalytic variant led to the scalemic targeted products presence 2,2-bis((4 R,5S)-4,5-diphenyl-4,5-dihydrooxazol-2-yl)acetonitrile (L2), as enantiopure cyano-bis(oxazoline) ligand. X-ray structure analysis pre-catalyst, for instance [Ni

Language: Английский

Citations

0