The
integration
of
metal
nanoparticles
and
solid
carriers
can
achieve
ideal
stability,
high
load
good
conductivity.
In
this
work,
copper
(Cu
NPs)
were
sequentially
deposited
on
a
cobalt
metal-organic
framework
(Co-MOF)
by
bonding
with
exposed
imino
groups,
followed
reduction
reaction
to
prepare
new
Cu@Co-MOF
composite.
acts
as
non-enzymatic
electrochemical
sensor
detect
glucose
(Glu)
in
an
alkaline
medium.
composite
working
electrode
Cu@Co-MOF/GCE
(GCE
=
glassy
carbon
electrode)
improves
the
electrocatalytic
activity
for
Glu
oxidation.
shows
excellent
performances
concentration
ranging
0.005~1.8
mmol∙L−1
(mM):
sensitivities
are
282.89
μA∙mM−1∙cm−2
0.005-0.4
mM
113.15
0.4-1.8
respectively
low
detection
limit
1.6
μM
(S/N
3)
selectivity
stability.
ACS Applied Polymer Materials,
Journal Year:
2023,
Volume and Issue:
5(8), P. 6186 - 6198
Published: July 7, 2023
Herein,
we
report
the
in-plane
growth
of
poly(3,4-ethylenedioxythiophene)
(PEDOT)
thin
films
and
their
composites,
such
as
PEDOT-copper
(PEDOT-Cu)
PEDOT-polythiophene
(PEDOT-PT),
on
a
nonconductive
substrate
by
alternating
current
(AC)-bipolar
electropolymerization
subsequent
use
wireless
electrodes
for
generation
luminol
electrochemiluminescence
(ECL).
By
using
gold
(Au)
wire
bipolar
electrode
(BPE),
PEDOT
film
was
initially
fabricated
exploiting
aforementioned
electrochemical
technique.
Successively,
fabrication
PEDOT-Cu
or
PEDOT-PT
composite
accomplished
AC-bipolar
electrolysis
step,
where
employed
BPE
to
drive
cathodic
electrodeposition
copper
particles
anodic
thiophene,
respectively.
Additionally,
all
polymer
were
further
BPEs
ECL,
which
resulted
in
an
intense
light
emission
that
could
be
imaged
with
common
digital
camera.
Interestingly,
have
found
intensity
spatial
distribution
generated
from
ECL
reaction
revealed
characteristics
different
can
correlated
conductivity
composition
material.
Analytical and Bioanalytical Chemistry,
Journal Year:
2022,
Volume and Issue:
414(27), P. 7935 - 7941
Published: Sept. 21, 2022
Cow's
milk
allergy
is
one
of
the
most
common
food
allergies
in
children
with
a
prevalence
around
2.5%.
Milk
contains
several
allergens;
main
ones
are
caseins
and
β-lactoglobulin
(β-LG).
At
regulatory
level,
β-LG
not
explicitly
named,
but
included
list
substances
or
products
causing
intolerances.
Hence,
presence
can
be
useful
marker
for
determining
food.
In
this
work,
we
present
an
aptasensor
based
on
electrochemiluminescence
(ECL)
quantification
real
matrices
displaying
integrated
advantages
consisting
high
specificity,
good
sensitivity,
portability,
cost
effectiveness.
The
performance
applicability
sensor
were
tested
by
analyzing
sample
skimmed
oat-based
drink
proposed
as
vegetable
substitute
animal
origin.
We
obtained
linear
correlation
between
intensity
signal
concentration
standard
solutions
(y
=
x
*
0.00653
+
1.038,
R2
0.99).
limit
detection
(LOD)
(LOQ)
found
to
1.36
4.55
μg
L-1,
respectively.
The
integration
of
metal
nanoparticles
and
solid
carriers
can
achieve
ideal
stability,
high
load
good
conductivity.
In
this
work,
copper
(Cu
NPs)
were
sequentially
deposited
on
a
cobalt
metal-organic
framework
(Co-MOF)
by
bonding
with
exposed
imino
groups,
followed
reduction
reaction
to
prepare
new
Cu@Co-MOF
composite.
acts
as
non-enzymatic
electrochemical
sensor
detect
glucose
(Glu)
in
an
alkaline
medium.
composite
working
electrode
Cu@Co-MOF/GCE
(GCE
=
glassy
carbon
electrode)
improves
the
electrocatalytic
activity
for
Glu
oxidation.
shows
excellent
performances
concentration
ranging
0.005~1.8
mmol∙L−1
(mM):
sensitivities
are
282.89
μA∙mM−1∙cm−2
0.005-0.4
mM
113.15
0.4-1.8
respectively
low
detection
limit
1.6
μM
(S/N
3)
selectivity
stability.
