Noble-Metal-Free Ultrathin CdS–NiFeS 2D–2D Heterojunction Nanosheets for Significantly Enhanced Photocatalytic Hydrogen Evolution DOI
Guotai Sun,

Zige Tai,

Fan Li

et al.

ACS Sustainable Chemistry & Engineering, Journal Year: 2023, Volume and Issue: 11(10), P. 4009 - 4019

Published: Feb. 24, 2023

To effectively restrain the charge recombination of bulk CdS, which dominantly limits photocatalytic activity, ultrathin CdS–NiFeS two-dimensional (2D)–2D heterojunctions are well designed with creation tight interfaces, where NiFeS nanosheets derived from layered double hydroxides possess tunable work functions and hydrogen evolution overpotentials. The optimized CdS–2% NiFe0.1S photocatalyst presents an excellent generation activity 626.7 μmol/h (10 mg catalysts, equivalent to 62.67 mmol/g/h), is fairly high among noble-metal-free CdS-based catalysts. greatly enhanced catalytic performance can be ascribed following synergetic effects. This 2D–2D heterostructure formed between CdS establishes sufficient contact shortens transport distance, efficiently accelerates electron transfer NiFeS, possesses a large function. Moreover, bimetallic cocatalyst evidently decreases reaction barrier, provides abundant active sites, then facilitates H2 generation. research may offer new inspirations develop 2D nanomaterials for outstanding performance.

Language: Английский

0D Pt anchoring on 2D/2D H2WO4/TiO2 S-scheme heterojunction for enhanced photocatalytic H2 evolution and simultaneous wastewater purification DOI
Gang Dong, Tianxiang Zhou,

Wenxuan Wei

et al.

International Journal of Hydrogen Energy, Journal Year: 2024, Volume and Issue: 60, P. 1309 - 1316

Published: Feb. 27, 2024

Language: Английский

Citations

9
Synergistic redox reactions toward co‐production of H2O2 and value‐added chemicals: Dual‐functional photocatalysis to achieving sustainability DOI Creative Commons
Brenden Jing Su,

Joel Jie Foo,

Grayson Zhi Sheng Ling

et al.

SusMat, Journal Year: 2024, Volume and Issue: 4(3)

Published: April 11, 2024

Abstract Integrating H 2 O evolution with oxidative organic synthesis in a semiconductor‐driven photoredox reaction is highly attractive since and high‐value chemicals can be concurrently produced using solar light as the only energy input. The dual‐functional photocatalytic approach, free from sacrificial agents, enables simultaneous production of chemicals. This strategy promises green sustainable minimal greenhouse gas emissions. In this review, we first elucidate fundamental principles cooperative integration selective oxidation utilization photoexcited electrons holes over semiconductor‐based photocatalysts. Afterwards, thorough review on recent advancements value‐added presented. Notably, in‐depth discussions insights into techniques for unravelling mechanisms are elucidated. Finally, critical challenges prospects thriving field comprehensively discussed. It envisioned that will serve pivotal guidance rational design such system, thereby further stimulating development economical environmentally benign production.

Language: Английский

Citations

9
Advance in the modification of g-C3N4-based composite for photocatalytic H2 production DOI
Jizhou Jiang,

Lianglang Yu,

Jiahe Peng

et al.

Carbon letters, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 20, 2025

Language: Английский

Citations

1
Evolutionary face-to-face 2D/2D bismuth-based heterojunction: The quest for sustainable photocatalytic applications DOI

Di Sen Chong,

Joel Jie Foo,

Xin‐Quan Tan

et al.

Applied Materials Today, Journal Year: 2022, Volume and Issue: 29, P. 101636 - 101636

Published: Sept. 23, 2022

Language: Английский

Citations

29
Noble-Metal-Free Ultrathin CdS–NiFeS 2D–2D Heterojunction Nanosheets for Significantly Enhanced Photocatalytic Hydrogen Evolution DOI
Guotai Sun,

Zige Tai,

Fan Li

et al.

ACS Sustainable Chemistry & Engineering, Journal Year: 2023, Volume and Issue: 11(10), P. 4009 - 4019

Published: Feb. 24, 2023

To effectively restrain the charge recombination of bulk CdS, which dominantly limits photocatalytic activity, ultrathin CdS–NiFeS two-dimensional (2D)–2D heterojunctions are well designed with creation tight interfaces, where NiFeS nanosheets derived from layered double hydroxides possess tunable work functions and hydrogen evolution overpotentials. The optimized CdS–2% NiFe0.1S photocatalyst presents an excellent generation activity 626.7 μmol/h (10 mg catalysts, equivalent to 62.67 mmol/g/h), is fairly high among noble-metal-free CdS-based catalysts. greatly enhanced catalytic performance can be ascribed following synergetic effects. This 2D–2D heterostructure formed between CdS establishes sufficient contact shortens transport distance, efficiently accelerates electron transfer NiFeS, possesses a large function. Moreover, bimetallic cocatalyst evidently decreases reaction barrier, provides abundant active sites, then facilitates H2 generation. research may offer new inspirations develop 2D nanomaterials for outstanding performance.

Language: Английский

Citations

22