Visible-light induced oxidation of thiols to disulfides using fluorescein as a metal free catalyst DOI

Pritesh P. Khobrekar,

Sandesh T. Bugde

Phosphorus, sulfur, and silicon and the related elements, Journal Year: 2025, Volume and Issue: unknown, P. 1 - 6

Published: Feb. 17, 2025

Language: Английский

Bioorthogonal Synthetic Chemistry Enabled by Visible‐Light Photocatalysis DOI Creative Commons
José L. Mascareñas, Mauro Mato,

Xulián Fernández-González

et al.

Angewandte Chemie International Edition, Journal Year: 2024, Volume and Issue: 63(47)

Published: Aug. 13, 2024

Abstract The field of bioorthogonal chemistry has revolutionized our ability to interrogate and manipulate biological systems at the molecular level. However, range chemical reactions that can operate efficiently in environments without interfering with native cellular machinery, remains limited. In this context, rapidly growing area photocatalysis offers a promising avenue for developing new type tools. inherent mildness, tunability, chemoselectivity, external controllability photocatalytic transformations make them particularly well‐suited applications living systems. This minireview summarizes recent advances technologies, particular focus on their potential enable selective generation designed products within biologically relevant or settings.

Language: Английский

Citations

6
Coupling of DNA Circuit and Templated Reactions for Quadratic Amplification and Release of Functional Molecules DOI
Ki Tae Kim, Simona Angerani, Dalu Chang

et al.

Journal of the American Chemical Society, Journal Year: 2019, Volume and Issue: 141(41), P. 16288 - 16295

Published: Sept. 20, 2019

DNA-based circuitry empowers logic gated operations and amplifications but is restricted to nucleic acid output. Templated reactions enable the translation of cues into diverse small-molecule outputs are more limited in their amplification. Herein, we demonstrate coupling a DNA circuit templated order achieve high levels amplification output small molecules, response input. We that allows for detection fM concentration analyte can respond with release cytotoxic drug.

Language: Английский

Citations

51
Recent advances in visible-light-mediated functionalization of olefins and alkynes using copper catalysts DOI

Arti Ramani,

Bhargav Desai, Bharatkumar Z. Dholakiya

et al.

Chemical Communications, Journal Year: 2022, Volume and Issue: 58(57), P. 7850 - 7873

Published: Jan. 1, 2022

Olefins and akynes are synthetically important building blocks in modern organic synthesis. This review highlights the recent developments direct functionalization of olefins alkynes via photoinduced copper-based catalysis.

Language: Английский

Citations

27
Counterion Effects in [Ru(bpy)3](X)2-Photocatalyzed Energy Transfer Reactions DOI Creative Commons

Juliette Zanzi,

Zachary Pastorel,

Carine Duhayon

et al.

JACS Au, Journal Year: 2024, Volume and Issue: 4(8), P. 3049 - 3057

Published: July 24, 2024

Photocatalysis that uses the energy of light to promote chemical transformations by exploiting reactivity excited-state molecules is at heart a virtuous dynamic within community. Visible-light metal-based photosensitizers are most prominent in organic synthesis, thanks their versatile ligand structure tunability allowing adjust photocatalytic properties toward specific applications. Nevertheless, large majority these photocatalysts cationic species whose counterion effects remain underestimated and overlooked. In this report, we show modification X counterions constitutive [Ru(bpy)

Language: Английский

Citations

5
Visible-light induced oxidation of thiols to disulfides using fluorescein as a metal free catalyst DOI

Pritesh P. Khobrekar,

Sandesh T. Bugde

Phosphorus, sulfur, and silicon and the related elements, Journal Year: 2025, Volume and Issue: unknown, P. 1 - 6

Published: Feb. 17, 2025

Language: Английский

Citations

0