Science China Chemistry, Journal Year: 2021, Volume and Issue: 64(8), P. 1332 - 1339
Published: July 20, 2021
Language: Английский
Chemical Reviews, Journal Year: 2021, Volume and Issue: 121(7), P. 3751 - 3891
Published: Feb. 25, 2021
Among the recent developments in metal-organic frameworks (MOFs), porous layered coordination polymers (CPs) have garnered attention due to their modular nature and tunable structures. These factors enable a number of properties applications, including gas guest sorption, storage separation gases small molecules, catalysis, luminescence, sensing, magnetism, energy conversion. MOFs, two-dimensional (2D) compounds are also known as 2D CPs or MOFs. Since discovery graphene 2004, materials been widely studied. Several MOFs suitable for exfoliation ultrathin nanosheets similar other materials, making these structures useful unique various technological applications. Furthermore, fascinating topological networks entanglements. This review provides an overview different aspects MOF architectures such topology, interpenetration, structural transformations, properties,
Language: Английский
Citations
686
Advanced Energy Materials, Journal Year: 2020, Volume and Issue: 10(38)
Published: Aug. 13, 2020
Abstract Electrocatalysis plays a critical role in clean energy conversion, enabling great improvement for future sustainable technologies. Single atom catalysts (SACs) derived from metal–organic framework (MOF) are emerging extraordinary materials electrochemical catalytic applications. Covering the merits of unique electronic structure, low‐coordination environment, quantum size effect, and metal–support interaction, SACs promise enhanced electrocatalytic activity, stability, selectivity field conversion. In this article, MOF synthesis routes to afford well‐dispersed along with respective mechanism systematically reviewed first, typical examples each strategy carefully discussed. Then characterization techniques understanding isolated spatial distribution, local coordination environment SACs, insights into stable mechanisms provided by density functional theory (DFT) calculations summarized. addition, several important applications MOF‐derived including oxygen reduction reaction, CO 2 nitrogen hydrogen evolution etc., highlighted. To facilitate development high‐performing technical challenges corresponding research directions proposed.
Language: Английский
Citations
339
Green Energy & Environment, Journal Year: 2022, Volume and Issue: 8(3), P. 698 - 721
Published: March 16, 2022
Water pollution is an increasingly serious environmental problem because many pollutants have carcinogenic effects on humans and aquatic organisms. Metal organic framework (MOF) made up of metal ions multifunctional ligands has been one the most concerned materials its adjustable regular pore structure. MOFs always shown attractive advantages in membrane separation adsorption technologies, among which water-stable are particularly prominent wastewater treatment (WWT) applications. This review systematically summarizes application MOF membranes filtration, pervaporation distillation. Also, mechanisms heavy metals, dyes antibacterials concluded. In order to tap full potential pristine sustainable treatment, current challenges discussed detail future research directions proposed.
Language: Английский
Citations
172
Journal of Energy Chemistry, Journal Year: 2023, Volume and Issue: 80, P. 625 - 657
Published: Feb. 14, 2023
Language: Английский
Citations
128
Advanced Energy Materials, Journal Year: 2021, Volume and Issue: 12(4)
Published: Jan. 18, 2021
Abstract The development of advanced energy conversion systems such as fuel cells and electrolyzers with desirable efficiency durability is great significance in order to power society a sustainable way, which highly depends on the fabrication electrocatalysts electrochemical performance. Multi‐scale design from atomic scale device‐scale crucial achieve optimal overall performance terms activity, selectivity, durability. Benefitting their diverse tunable structures compositions, metal–organic frameworks (MOFs) are promising platforms synthesize at multiple scales for electrocatalysis. Herein, fundamental principles recent progress multi‐scale MOF‐derived materials aspects active sites, interfaces, pore structures, morphologies summarized. Moreover, precise control these variables, meet requirements specific energy‐related reactions including oxygen reduction reaction, evolution hydrogen CO 2 reaction (CO RR), N critically discussed. Furthermore, challenges future research directions real‐world applications provided.
Language: Английский
Citations
125
Materials Today, Journal Year: 2021, Volume and Issue: 44, P. 78 - 104
Published: Jan. 12, 2021
Language: Английский
Citations
122
Science China Chemistry, Journal Year: 2021, Volume and Issue: 64(8), P. 1267 - 1282
Published: April 27, 2021
Language: Английский
Citations
112
ACS Nano, Journal Year: 2021, Volume and Issue: 15(8), P. 12741 - 12767
Published: Aug. 5, 2021
Metal anodes based on a plating/stripping electrochemistry such as metallic Li, Na, K, Zn, Ca, Mg, Fe, and Al are recognized promising anode materials for constructing next-generation high-energy-density rechargeable metal batteries owing to their low electrochemical potential, high theoretical specific capacity, superior electronic conductivity, etc. However, inherent issues chemical reactivity, severe growth of dendrites, huge volume changes, unstable interface largely impede practical application. Covalent organic frameworks (COFs) derivatives emerging multifunctional have already well addressed the in past several years due abundant metallophilic functional groups, special inner channels, controllable structures. COFs can solve by interfacial modification, homogenizing ion flux, acting nucleation seeds, reducing corrosion anodes, so on. Nevertheless, related reviews still absent. Here we present detailed review batteries. Meanwhile, some outlooks opinions put forward. We believe catch eyes relevant researchers supply inspiration future research.
Language: Английский
Citations
112
Coordination Chemistry Reviews, Journal Year: 2022, Volume and Issue: 468, P. 214595 - 214595
Published: May 30, 2022
Language: Английский
Citations
112
Chemical Society Reviews, Journal Year: 2022, Volume and Issue: 51(7), P. 2491 - 2543
Published: Jan. 1, 2022
Although the term 'confinement' regularly appears in electrochemical literature, elevated by continuous progression research of nanomaterials and nanostructures, up until today various aspects confinement considered electrochemistry are rather scattered individual contributions outside established disciplines this field. Thanks to a number highly original publications growing appreciation as an overarching link between different exciting new strategies, 'electrochemistry under confinement' is process forming discipline its own. To aid development coherent terminology joint basic concepts, crucial factors for transformation, review provides overview on effects processes known date that can be caused confinement. It also suggests where boundaries other effects, such nano-effects could drawn. conceptualize vast amount activities revolving around main concepts confinement, we define six types select two them discuss state art anticipated future developments more detail. The first type concerns nanochannel environments their applications electrodeposition sensing. second covers newly emerging field colloidal single entity electrochemistry. In these contexts, will instance address influence mass transport electric distributions associated changes local species concentration or driving force altered reaction kinetics product selectivity. Highlighting pioneering works recent developments, educational does not only aim at surveying categorizing state-of-the-art, but seeks specifically point out perspectives confinement-controlled
Language: Английский
Citations
96