Toward the Customized Performance on a Supported Au₄Ru₂ Cluster Catalyst

Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 21, 2025

Abstract Precisely constructing the catalyst structure and composition at atomic level is highly desirable for unexpected properties, but extremely challenging. The success in atomically precise nanochemistry provides an opportunity active site‐tailoring of catalysts toward unique catalysis. Here, monodisperse Au 4 Ru 2 (PPh 3 ) (SC H Ph) 8 clusters are reported that anchored into aerogel as heterogeneous carbonylation process CO hydrogenation coupled with dimethylamine. indeed a performance stage cluster, on which sites cluster act centers to participate synergistic activation reaction , thereby promoting formylation N,N ‐dimethylformamide (DMF), while play decisive role sequent DMF trimethylamine. Notably, can not only exhibit high turnover number performed batch reactor, also show long‐term utilization flowing fixed‐bed system, have been documented previous catalysts.

Language: Английский

Conversion of atmospheric CO2 catalyzed by thiolate-based ionic liquids under mild conditions: efficient synthesis of 2-oxazolidinones

Organic & Biomolecular Chemistry, Journal Year: 2024, Volume and Issue: 22(40), P. 8138 - 8143

Published: Jan. 1, 2024

Thiolate-based ionic liquids, specifically the catalyst [TBP][2-Tp], have demonstrated their efficiency in catalyzing reaction of CO

Language: Английский

Recent advances in N-formylation reaction for the chemical recycling of carbon dioxide

Green Chemistry, Journal Year: 2024, Volume and Issue: unknown

Published: Jan. 1, 2024

The homogeneous and heterogeneous catalyst systems applied in N -formylation reaction of amines CO 2 from both are summarized.

Language: Английский