Post-synthetic modification of amine-functionalized permanently porous coordination cages DOI Creative Commons

Jahidul Hoq,

Michael R. Dworzak,

Darshanamala Dissanayake

et al.

Chemical Communications, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 4, 2024

This manuscript explores the post-synthetic modification (PSM) of amine-functionalized porous coordination cages, specifically focusing on formation imine bonds through reactions with aldehydes. Targeting various cage topologies, including zirconium-, magnesium-, and molybdenum-based structures, we demonstrate tunability solubility porosity selective functionalization where proximity amine groups parent impacts extent modification. The work highlights reversible nature formation, offering potential applications in switching mixed-metal solid synthesis.

Language: Английский

Double-Bridging Increases the Stability of Zinc(II) Metal–Organic Cages DOI Creative Commons

Hannah Kurz,

Paula C. P. Teeuwen, Tanya K. Ronson

et al.

Journal of the American Chemical Society, Journal Year: 2024, Volume and Issue: 146(45), P. 30958 - 30965

Published: Nov. 4, 2024

A key feature of coordination cages is the dynamic nature their coordinative bonds, which facilitates synthesis complex polyhedral structures and post-assembly modification. However, this can limit cage stability. Increasing robustness important for real-world use cases. Here we introduce a double-bridging strategy to increase stability, where designed pairs bifunctional subcomponents combine generate rectangular tetratopic ligands within pseudo-cubic Zn8L6 cages. These withstand transmetalation, addition competing ligands, nucleophilic imines, under conditions single-bridged congeners decompose. Our approach not only increases stability while maintaining structure, but also enables incorporation additional functional units in proximity cavity. The larger cages, are inaccessible as congeners.

Language: Английский

Citations

1
Tunable Synthesis of Heteroleptic Zirconium-Based Porous Coordination Cages DOI Creative Commons
Merissa N. Morey,

Christine M. Montone,

Michael R. Dworzak

et al.

Chemical Science, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 18, 2024

A mixed-ligand synthesis yields zirconium-based cages with tunable functional group ratios, enabling diverse ligand incorporation, including previously elusive ones, via a straightforward one-pot strategy.

Language: Английский

Citations

1
Post-synthetic modification of amine-functionalized permanently porous coordination cages DOI Creative Commons

Jahidul Hoq,

Michael R. Dworzak,

Darshanamala Dissanayake

et al.

Chemical Communications, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 4, 2024

This manuscript explores the post-synthetic modification (PSM) of amine-functionalized porous coordination cages, specifically focusing on formation imine bonds through reactions with aldehydes. Targeting various cage topologies, including zirconium-, magnesium-, and molybdenum-based structures, we demonstrate tunability solubility porosity selective functionalization where proximity amine groups parent impacts extent modification. The work highlights reversible nature formation, offering potential applications in switching mixed-metal solid synthesis.

Language: Английский

Citations

0