Cited by The Capacity of the R[OE(C6F5)2]2 (E = B, Al; R = C2H4, p-C6H4, m-C6H4) Complexes with Pyrazine and 3,3′-Bipyridine Towards Activation of Hydrogen Molecules

Synthesis and Structures of Bidentate Lewis Acid Complexes R[OB(C6F5)2]2 (R = C2H4, p-C6H4) with Pyrazine DOI

P. I. Kudina,

Mariya A. Kryukova, Igor V. Kazakov

et al.

Journal of Structural Chemistry, Journal Year: 2025, Volume and Issue: 66(2), P. 346 - 352

Published: Feb. 1, 2025

Language: Английский

Citations

Reactions of 1,1- and 1,2-bis-boranes with a Protic Diamine and Hydrazine Ł DOI

Jason Yeung,

Amir Yeganeh-Salman,

Linkun Miao

et al.

Dalton Transactions, Journal Year: 2024, Volume and Issue: unknown

Published: Jan. 1, 2024

The reactions of 1,1- and 1,2-bis-boranes, PhCH 2 CH(B(C 6 F 5 ) 1 Me 3 SiCH(B(C )CH B(C 2, with o -phenylenediamine hydrazine are described. these adducts the impact acidity NH groups explored.

Language: Английский

Citations

Facile synthesis of bidentate boron Lewis acids by pentafluorobenzene elimination DOI

P. I. Kudina,

Anna S. Lisovenko, Mariya A. Kryukova

et al.

European Journal of Inorganic Chemistry, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 5, 2024

Abstract The obtained results reveal simple synthetic approach for bidentate boron Lewis acids with the ‐OB(C 6 F 5 ) 2 acid group and aliphatic or aromatic linkers. Computational showed comparable FIA site in relative to initial B(C 3 . strength of R[OB(C ] (R=C H 4 , p‐C m‐C was characterized by Gutman‐Beckett tests. elimination pentafluorobenzene reaction R‐OH can be used synthesis R‐OB(C derivatives polydentate strong acids.

Language: Английский

Citations

Tri‐ and Hexadentate Poly‐Lewis Acids – Attempts to Unravel the Complex Dynamics of Cage and Capsule Formation in Solution DOI

Maximilian J. Klingsiek, Maurice Franke,

Simon M. Walkenhorst

et al.

European Journal of Inorganic Chemistry, Journal Year: 2024, Volume and Issue: 27(31)

Published: Aug. 6, 2024

Abstract Two tri‐ and two hexadentate poly‐Lewis acids (PLAs) with calyx‐like structures of C 3 symmetry containing aluminum‐ boron‐containing Lewis acidic functions were prepared by tin‐metal exchange reactions. The triply hydrosilylated [12]annulene served as basic framework. It forms a structure the stereo‐ regioselective attachment three SiMeCl 2 groups to planar [12]annulene. PLA precursors generated attaching or six trimethylstannylethynyl silicon atoms. acid introduced using reagents bis‐(bis(trimethylsilyl)methyl)aluminium hydride (HAl[CH(SiMe ) ] catecholatochloroborane (ClBCat). complexation behavior PLAs towards different bases was investigated NMR. Bases included pyridine, polydentate nitrogen‐ phosphorus‐containing bases. Additionally, molecules bidentate base captured PLAs. Diffusion NMR experiments provided insight into aggregation processes: some adducts had significantly larger volume than expected, indicating formation expected 1 : adduct, including adduct cages. distances between units steric requirement attached substituents determine Thus, weak BCat show no (tridentate case) strong (hexadentate interaction PMe ‐containing bases, if they can act cooperatively.

Language: Английский

Citations

Colored Complexes of Bidentate Lewis Acids R[OB(C6F5)2]2 (R = 1,4-C6H4, 1,4-C6F4) with Pyrazine DOI

P. I. Kudina,

Ekaterina V. Glukhovich,

Igor V. Kazakov

et al.

Russian Journal of General Chemistry, Journal Year: 2024, Volume and Issue: 94(11), P. 2915 - 2919

Published: Nov. 1, 2024

Language: Английский

Citations

The Capacity of the R[OE(C6F5)2]2 (E = B, Al; R = C2H4, p-C6H4, m-C6H4) Complexes with Pyrazine and 3,3′-Bipyridine Towards Activation of Hydrogen Molecules DOI

Anna S. Lisovenko, Igor V. Kazakov

Russian Journal of General Chemistry, Journal Year: 2024, Volume and Issue: 94(12), P. 3296 - 3302

Published: Dec. 1, 2024

Language: Английский

Citations