Enantioselective Synthesis of Axially Chiral Silacyclohexylidene Oxime Ethers by Chiral Phosphoric Acid Catalysis DOI
Xiyu Wang, Xingang Xie, Zhongwei Wu

et al.

Synthesis, Journal Year: 2024, Volume and Issue: unknown

Published: Oct. 17, 2024

Abstract The first asymmetric condensation of prochiral silacyclohexanones with hydroxylamines by chiral phosphoric acid catalysis has been developed, which provides a facile and straightforward protocol for the enantioselective construction valuable axially silacyclohexylidene oxime ethers that are otherwise inaccessible. Notably, this constitutes rare example accessing silacycles featuring axial chirality.

Language: Английский

Enantioselective Synthesis of Axially Chiral Alkylidenecycloalkanes via Copper-Catalyzed Functionalization of Acyl Allenols DOI

Baihui Gong,

Qing‐Bin Lu,

R. Li-jiun Sun

et al.

ACS Catalysis, Journal Year: 2025, Volume and Issue: unknown, P. 2351 - 2358

Published: Jan. 24, 2025

Language: Английский

Citations

1
Cu-catalyzed enantioselective assembly of axially chiral allylic boronates DOI
Shuai Wang, Jianbo Liu,

Wenyue Ma

et al.

Science China Chemistry, Journal Year: 2024, Volume and Issue: unknown

Published: Oct. 25, 2024

Language: Английский

Citations

4
Rh(I)-Catalyzed Modular Synthesis of Axially Chiral Alkylidene Azacycloalkanes DOI Creative Commons
Yang Chen, Jiayan Chen, Shifa Zhu

et al.

ACS Central Science, Journal Year: 2025, Volume and Issue: unknown

Published: May 11, 2025

Language: Английский

Citations

0
Enantioselective Synthesis of Axially Chiral Silacyclohexylidene Oxime Ethers by Chiral Phosphoric Acid Catalysis DOI
Xiyu Wang, Xingang Xie, Zhongwei Wu

et al.

Synthesis, Journal Year: 2024, Volume and Issue: unknown

Published: Oct. 17, 2024

Abstract The first asymmetric condensation of prochiral silacyclohexanones with hydroxylamines by chiral phosphoric acid catalysis has been developed, which provides a facile and straightforward protocol for the enantioselective construction valuable axially silacyclohexylidene oxime ethers that are otherwise inaccessible. Notably, this constitutes rare example accessing silacycles featuring axial chirality.

Language: Английский

Citations

0