Precise Photochemical Post‐Processing of Molecular Crystals DOI

Jianqun Qi,

Linfeng Lan, Quanliang Chen

et al.

Angewandte Chemie, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 19, 2024

Abstract Molecular crystals carry a great potential as new soft smart materials, with plethora of recent examples overcoming the major obstacle mechanical flexibility, and this research direction holds enormous to revolutionize optics, electronics, medicine, space exploration. However, shaping organic into desired shapes sizes remains practical challenge due lack control over crystallization process, difficulties in post‐processing without introduction defects that are usually imparted by their nature. Here we present an innovative approach employs photochemical processing for precise nondestructive cutting molecular crystal. Our proposed method uses light post‐process size shape, similar using cut other materials. This reaction induces strain, ensuring sharp cleavage need melting or processes. We further demonstrate producing arbitrary size, which can be used controllable optical waveguides. Among applications, prepare dynamic crystals, particularly those aspect ratios crucial deformation, such flexible robotics, sensing.

Language: Английский

A Micromechanical Model for Light-Interactive Molecular Crystals DOI
Deepak Kumar Tiwari, Ananya Renuka Balakrishna

Published: Jan. 1, 2025

Language: Английский

Citations

0
Crystallizing covalent organic frameworks from metal organic framework through chemical induced-phase engineering DOI Creative Commons
Abdul Khayum Mohammed, Safa Gaber, Jésus Raya

et al.

Scientific Reports, Journal Year: 2023, Volume and Issue: 13(1)

Published: Nov. 9, 2023

The ordered porous frameworks like MOFs and COFs are generally constructed using the monomers through distinctive metal-coordinated covalent linkages. Meanwhile, inter-structural transition between each class of these materials is an under-explored research area. However, such altered expected to have exciting features compared their pristine versions. Herein, we demonstrated a chemical-induction phase-engineering strategy transform two-dimensional conjugated Cu-based SA-MOF (Cu-Tp) into 2D-COFs (Cu-TpCOFs). structural phase offered in-situ pore size engineering from 1.1 nm 1.5-2.0 nm. Moreover, Cu-TpCOFs showed uniform low percentage-doped (~ 1-1.5%) metal distribution improved crystallinity, porosity, stability parent Cu-Tp MOF. construction framework another with new linkages opens interesting opportunities for phase-engineering.

Language: Английский

Citations

4
Precise Photochemical Post‐Processing of Molecular Crystals DOI

Jianqun Qi,

Linfeng Lan, Quan‐Liang Chen

et al.

Angewandte Chemie International Edition, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 19, 2024

Abstract Molecular crystals carry a great potential as new soft smart materials, with plethora of recent examples overcoming the major obstacle mechanical flexibility, and this research direction holds enormous to revolutionize optics, electronics, medicine, space exploration. However, shaping organic into desired shapes sizes remains practical challenge due lack control over crystallization process, difficulties in post‐processing without introduction defects that are usually imparted by their nature. Here we present an innovative approach employs photochemical processing for precise nondestructive cutting molecular crystal. Our proposed method uses light post‐process size shape, similar using cut other materials. This reaction induces strain, ensuring sharp cleavage need melting or processes. We further demonstrate producing arbitrary size, which can be used controllable optical waveguides. Among applications, prepare dynamic crystals, particularly those aspect ratios crucial deformation, such flexible robotics, sensing.

Language: Английский

Citations

1
Precise Photochemical Post‐Processing of Molecular Crystals DOI

Jianqun Qi,

Linfeng Lan, Quanliang Chen

et al.

Angewandte Chemie, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 19, 2024

Abstract Molecular crystals carry a great potential as new soft smart materials, with plethora of recent examples overcoming the major obstacle mechanical flexibility, and this research direction holds enormous to revolutionize optics, electronics, medicine, space exploration. However, shaping organic into desired shapes sizes remains practical challenge due lack control over crystallization process, difficulties in post‐processing without introduction defects that are usually imparted by their nature. Here we present an innovative approach employs photochemical processing for precise nondestructive cutting molecular crystal. Our proposed method uses light post‐process size shape, similar using cut other materials. This reaction induces strain, ensuring sharp cleavage need melting or processes. We further demonstrate producing arbitrary size, which can be used controllable optical waveguides. Among applications, prepare dynamic crystals, particularly those aspect ratios crucial deformation, such flexible robotics, sensing.

Language: Английский

Citations

0