Study on the Performance of Aqueous Aluminum‐Ion Battery with Al[TFSI]3 Electrolyte DOI Open Access
Yajie Zhou, Zhaohua Li, Xinwen Chen

et al.

Energy Technology, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 18, 2024

Aqueous aluminum‐ion batteries have higher energy density and lower cost than traditional rechargeable batteries. Electrolytes play a vital role in aqueous battery are directly related to performance. However, ionic liquid electrolytes suitable for aluminum expensive potential environmental problems. To improve the reduce impact, this study innovatively proposes new electrolyte. In article, preparation performance testing bench is built prepare battery. A novel proposed using α‐MnO 2 as positive electrode, eutectic mixture‐coated anode (UTAl) negative bistrifluoromethanesulfonate (Al[TFSI] 3 ) solution The electrochemical of prepared studied under multiple working conditions. results show that assembled UTAl/Al[TFSI] /α‐MnO exhibits an ultrahigh first‐cycle specific up 420 mAh g −1 at room temperature current 50 mA 5 mol L Al[TFSI] . newly developed can achieve capacity retention rate 63.4%, Coulombic efficiency over 94%, stable charge discharge voltage platform 1.65 1.4 V.

Language: Английский

Improved Mn4+/Mn2+ Contribution in High‐Voltage Zn–MnO2 Batteries Enabled by an Al3+‐Ion Electrolyte DOI Open Access
Xingqi Chang, Jesús Chacón‐Borrero, Jian Ku Shang

et al.

Advanced Energy Materials, Journal Year: 2024, Volume and Issue: 14(48)

Published: Aug. 27, 2024

Abstract Rechargeable aqueous Zn–MnO 2 batteries are attracting attention as a cost‐effective and safe energy storage solution, but their commercialization faces challenges due to limited stability, output voltage, density. Herein, hybrid‐ion system with enhanced Mn 4+ /Mn 2+ electrochemical contribution is introduced using an Al 3+ ‐based electrolyte. Compared conventional Zn electrolytes, the hybrid /Zn cell offers higher voltage of 1.75 V, capacities up 469 mAh g −1 , outstanding densities ≈730 Wh kg at 0.3 A . Besides, ‐enabled battery shows 100% capacity density retention after 10,000 cycles Even high mass–loading 6.2 mg cm −2 ≈200 maintained for over 100 cycles. This performance related different intercalation reaction mechanisms, proved by combination analysis ex‐situ x ‐ray diffraction characterization cells discharge stages. ions, Lewis strong acid, contribute in two significant ways: through highly reversible intercalation/de‐intercalation that substantially boosts capacitance low current rates, promoting aided H + dominates rates. Overall, this work demonstrates practical potential low‐cost stationary habilitated multiple ion co‐intercalation.

Language: Английский

Citations

4
Advanced Aqueous Electrolytes for Aluminum-Ion Batteries: Challenges and Opportunities DOI
Michael Ruby Raj, Karim Zaghib, Gibaek Lee

et al.

Energy storage materials, Journal Year: 2025, Volume and Issue: unknown, P. 104211 - 104211

Published: March 1, 2025

Language: Английский

Citations

0
Recent Advances in In Situ Characterization of the Electrochemical Processes at the Alloy Anode-Electrolyte Interfaces DOI
Ruizhi Liu,

Rui Wen

Langmuir, Journal Year: 2025, Volume and Issue: unknown

Published: March 6, 2025

Lithium-metal batteries (LMBs) have garnered widespread attention due to their high energy density. Alloy anodes are particularly notable for exceptional specific capacity used in LMBs. However, alloy encounter significant challenges interfacial issues, which include sluggish reaction kinetics and mechanical failures induced by force-electric coupling at the interface. In situ characterization of interface evolution is crucial gain a deeper understanding fundamental origins these issues. This review systematically examines associated with highlights role techniques elucidating kinetics, mechanisms, dendrite formation anode-electrolyte The future development this field proposed outlook.

Language: Английский

Citations

0
Beyond Lithium: Future Battery Technologies for Sustainable Energy Storage DOI Creative Commons
Alan K. X. Tan, Shiladitya Paul

Energies, Journal Year: 2024, Volume and Issue: 17(22), P. 5768 - 5768

Published: Nov. 18, 2024

Known for their high energy density, lithium-ion batteries have become ubiquitous in today’s technology landscape. However, they face critical challenges terms of safety, availability, and sustainability. With the increasing global demand energy, there is a growing need alternative, efficient, sustainable storage solutions. This driving research into non-lithium battery systems. paper presents comprehensive literature review on recent advancements technologies, specifically sodium-ion, potassium-ion, magnesium-ion, aluminium-ion, zinc-ion, calcium-ion batteries. By consulting peer-reviewed articles reviews, we examine key electrochemical properties underlying chemistry each system. Additionally, evaluate safety considerations, environmental sustainability, recyclability. The reviewed highlights promising potential to address limitations batteries, likely facilitate scalable solutions across diverse applications.

Language: Английский

Citations

2
Study on the Performance of Aqueous Aluminum‐Ion Battery with Al[TFSI]3 Electrolyte DOI Open Access
Yajie Zhou, Zhaohua Li, Xinwen Chen

et al.

Energy Technology, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 18, 2024

Aqueous aluminum‐ion batteries have higher energy density and lower cost than traditional rechargeable batteries. Electrolytes play a vital role in aqueous battery are directly related to performance. However, ionic liquid electrolytes suitable for aluminum expensive potential environmental problems. To improve the reduce impact, this study innovatively proposes new electrolyte. In article, preparation performance testing bench is built prepare battery. A novel proposed using α‐MnO 2 as positive electrode, eutectic mixture‐coated anode (UTAl) negative bistrifluoromethanesulfonate (Al[TFSI] 3 ) solution The electrochemical of prepared studied under multiple working conditions. results show that assembled UTAl/Al[TFSI] /α‐MnO exhibits an ultrahigh first‐cycle specific up 420 mAh g −1 at room temperature current 50 mA 5 mol L Al[TFSI] . newly developed can achieve capacity retention rate 63.4%, Coulombic efficiency over 94%, stable charge discharge voltage platform 1.65 1.4 V.

Language: Английский

Citations

0