Cu(II)/Photoredox-Catalyzed Aminoacylation of Vinyl Bromides DOI
Guojin Huang, Huanfeng Jiang, Qiang Zeng

et al.

Organic Letters, Journal Year: 2025, Volume and Issue: unknown

Published: March 24, 2025

A novel C–C coupling reaction of vinyl bromides with carboxamides has been developed through Cu(OAc)2/photocatalysis. This process features regioselective carboxamido carbon-vinylation under mild conditions. Mechanistic studies suggest that the formation an acyl-Cu(I) intermediate plays a crucial role regard to enabling this transformation.

Language: Английский

Cu(II)/Photoredox-Catalyzed Aminoacylation of Vinyl Bromides DOI
Guojin Huang, Huanfeng Jiang, Qiang Zeng

et al.

Organic Letters, Journal Year: 2025, Volume and Issue: unknown

Published: March 24, 2025

A novel C–C coupling reaction of vinyl bromides with carboxamides has been developed through Cu(OAc)2/photocatalysis. This process features regioselective carboxamido carbon-vinylation under mild conditions. Mechanistic studies suggest that the formation an acyl-Cu(I) intermediate plays a crucial role regard to enabling this transformation.

Language: Английский

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