Progress in defect engineering strategies to enhance piezoelectric catalysis for efficient water treatment and energy regeneration

Separation and Purification Technology, Journal Year: 2023, Volume and Issue: 330, P. 125247 - 125247

Published: Oct. 5, 2023

Language: Английский

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Mechanochemical Synthesis of Aryl Fluorides by Using Ball Milling and a Piezoelectric Material as the Redox Catalyst

Angewandte Chemie International Edition, Journal Year: 2023, Volume and Issue: 62(39)

Published: July 31, 2023

Abstract Aryl fluorides are important structural motifs in many pharmaceuticals. Although the Balz–Schiemann reaction provides an entry to aryl from aryldiazonium tetrafluoroborates, it suffers drawbacks such as long time, high temperature, toxic solvent, gas release, and low functional group tolerance. Here, we describe a general method for synthesis of tetrafluoroborates using piezoelectric material redox catalyst under ball milling conditions presence Selectfluor. This approach effectively addresses aforementioned limitations. Furthermore, can be recycled multiple times. Mechanistic investigations indicate that this fluorination may proceed via radical pathway, Selectfluor plays dual role both source fluorine terminal reductant.

Language: Английский

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Mechanical‐Force‐Induced Non‐spontaneous Dehalogenative Deuteration of Aromatic Iodides Enabled by Using Piezoelectric Materials as a Redox Catalyst

Angewandte Chemie International Edition, Journal Year: 2024, Volume and Issue: 63(28)

Published: April 30, 2024

Abstract The development of green and efficient deuteration methods is great significance for various fields such as organic synthesis, analytical chemistry, medicinal chemistry. Herein, we have developed a dehalogenative strategy using piezoelectric materials catalysts in solid‐phase system under ball‐milling conditions. This non‐spontaneous reaction induced by mechanical force. D 2 O can serve both deuterium source an electron donor the transformation, eliminating need additional stoichiometric exogenous reductants. A series (hetero)aryl iodides be transformed into deuterated products with high incorporation. method not only effectively overcomes existing synthetic challenges but also used labelling drug molecules derivatives. Bioactivity experiments molecule suggest that D‐ipriflavone enhances inhibitory effects on osteoclast differentiation BMDMs vitro .

Language: Английский

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Resonant acoustic mixing (RAM) for efficient mechanoredox catalysis without grinding or impact media

Chemical Communications, Journal Year: 2022, Volume and Issue: 59(8), P. 1010 - 1013

Published: Dec. 12, 2022

Resonant acoustic mixing (RAM) enables mechanoredox catalysis with BaTiO3 as the piezoelectric catalyst on model diazonium coupling reactions. RAM proceeds without formal grinding or impact media, is faster than analogous ball-milling strategy, and readily scalable. X-ray diffraction spectroscopy indicate that reusability of a under might be limited by boration.

Language: Английский

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Strongly piezocatalytic dye decomposition of sol-gel synthesized PZT film

Ceramics International, Journal Year: 2023, Volume and Issue: 50(1), P. 2514 - 2520

Published: Nov. 2, 2023

Language: Английский

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Insight into the synergistic mechanism of sonolysis and sono-induced BiFeO3 nanorods piezocatalysis in atenolol degradation: Ultrasonic parameters, ROS and degradation pathways

Chemosphere, Journal Year: 2023, Volume and Issue: 335, P. 139084 - 139084

Published: May 30, 2023

Language: Английский

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Discovery of molecular ferroelectric catalytic annulation for quinolines

Nature Communications, Journal Year: 2024, Volume and Issue: 15(1)

Published: Aug. 7, 2024

Ferroelectrics as emerging and attractive catalysts have shown tremendous potential for applications including wastewater treatment, hydrogen production, nitrogen fixation, organic synthesis, etc. In this study, we demonstrate that molecular ferroelectric crystal TMCM-CdCl3 (TMCM = trimethylchloromethylammonium) with multiaxial ferroelectricity superior piezoelectricity has an effective catalytic activity on the direct construction of pharmacologically important substituted quinoline derivatives via one-pot [3 + 2 1] annulation anilines terminal alkynes by using N,N-dimethylformamide (DMF) carbon source. The recrystallized crystals from DMF remain well piezoelectricity. Upon ultrasonic condition, periodic changes in polarization contribute to release free charges surface domains nano size, which then quickly interacts substrates solution trigger pivotal redox process. Our work advances a route not only providing valuable direction ferroelectrics but also further enriching executable range catalysis. Molecular possess switchable spontaneous polarization. Here, authors show demonstrates evident effects synthesis quinolines.

Language: Английский

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Organic Reactions Enabled by Mechanical Force‐Induced Single Electron Transfer

Chemistry - A European Journal, Journal Year: 2024, Volume and Issue: 30(47)

Published: June 18, 2024

Mechanochemical reactions, achieved through milling, grinding, or other mechanical actions, have emerged as a solvent-free alternative to traditional solution-based chemistry. Mechanochemistry not only provides the opportunity eliminate bulk solvent use, reducing waste generation, but also unveils new reaction strategy which enables realization of reactions previously inaccessible in solution. While majority organic facilitated by force traditionally follow two-electron transfer pathways similar their counterparts, field mechanochemically induced single-electron (SET) has witnessed rapid development. This review outlines examples mechanochemical SET process, focusing on reagents that initiate SET, thereby positioning mechanochemistry burgeoning within realm

Language: Английский

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Mechanochemical Vicinal Dibromination of Unactivated Alkenes and Alkynes Using Piezoelectric Material as a Redox Catalyst

Organic Letters, Journal Year: 2024, Volume and Issue: 26(20), P. 4240 - 4245

Published: May 14, 2024

Mechanoredox chemistry is a rapidly evolving field at the intersection of mechanical forces and chemical reactions. Herein, we have reported vicinal dibromination unsaturated hydrocarbons using piezoelectric material (Li2TiO3) as redox catalyst. Furthermore, reaction can be efficiently scaled up to 10 mmol performed under an air atmosphere room temperature without solvents or external reductants, Li2TiO3 reused multiple times structural change.

Language: Английский

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Mechanoredox‐Catalyzed Organic Synthesis with Piezoelectric Materials: Quo Vadis?

ChemCatChem, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 24, 2025

Abstract Piezoelectric materials offer great promise due to their ability generate electric fields under mechanical stress, producing surface charges that drive otherwise kinetically sluggish redox reactions. The strained surfaces of these provide a unique advantage in controlling product selectivity and enabling reaction pathways are unattainable with conventional methods. This perspective highlights advancements, challenges, the future potential piezoelectric synthetic organic chemistry, focus on designing optimized for piezocatalyzed synthesis. Piezocatalysis is industrially relevant because its operational simplicity, mild, gram scale synthesis reusable catalysts, minimal solvent use, air tolerant conditions. It involves cycles facilitate one electron events without requiring light exposure or electrical bias. Despite significant progress, many fundamental aspects yet be fully understood. One example correlation between piezoelectricity catalytic activity, which not always linear, as demonstrated by comparison tetragonal cubic BaTiO₃. While BaTiO₃ piezoelectric, it shows excellent activity certain reactions such arylation, dicarbonylation, cyclization mechanochemical conditions comparable Considering all aspects, this aims stimulate discussion advance promising field right direction.

Language: Английский

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