New Concept on the Generation and Regulation of Circularly Polarized Luminescence DOI Open Access
Gong Zhang, Wei Zhang

Chemistry - A European Journal, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 12, 2024

Circularly polarized luminescence (CPL) has attracted tremendous attention because of its significant application prospect across multiple fields three-dimensional display, data storage, and information encryption. Chirality are two necessary prerequisites for the generation CPL. However, controlling these factors simultaneously in a rational manner remains challenge. Herein, we highlight recent advances on regulation CPL through new concept, named matching rules, mainly including fluorescence-selective absorption, circularly fluorescence energy transfer, chiral communication between excited state ground state. An important commonality among strategies is that they need good overlap corresponding spectra luminescent part (fluorescence, phosphorescence, or CPL) (organic, inorganic, organic-inorganic hybrid materials), which can be contactless separate. Different from most previous studies, no covalent noncovalent interactions parts required, makes them more facile convenient. Finally, summarize main advantages current challenges. We expect this concept to offer insightful novel understanding inspiration regulation.

Language: Английский

Chiral structures in azobenzene‐containing systems: Construction, regulation, and application DOI Creative Commons

Zixiang He,

Xiaoxiao Cheng, Zhao Wang

et al.

Deleted Journal, Journal Year: 2024, Volume and Issue: 2(2)

Published: May 1, 2024

Abstract Chirality is a fundamental property in nature, which essential for the existence and survival of living organisms. Smart responsive chiroptical materials have garnered increasing attention due to their unique structural characteristics potential applications. Among these, azobenzene (Azo), as typical photoresponsive chromophore, plays crucial role constructing controlling chiral structures. The cis ‐ trans isomerization, liquid crystallinity, other physicochemical properties allow wide range tunability stimuli‐responsive materials. Herein, we review research studies field chiral/achiral Azo building blocks multilevel generation well switching, summarize recent advances on applications structures from micro macro levels. Finally, aim provide an overview challenges new opportunities development novel smart

Language: Английский

Citations

13
Visible‐Light‐Mediated Photocatalyst‐Free Hydroacylation of Azodicarboxylic Acid Derivatives with 4‐Acyl‐1,4‐dihydropyridines DOI
Li Liu, Jing Wang, Xiaoying Feng

et al.

Chinese Journal of Chemistry, Journal Year: 2024, Volume and Issue: 42(11), P. 1230 - 1236

Published: Feb. 5, 2024

Comprehensive Summary A visible‐light‐enabled, photocatalyst‐free hydroacylation reaction of azodicarboxylic acid derivatives was described. This radical conjugate addition (RCA) protocol relied on the dual role 4‐acyl‐1,4‐dihydropyridine (acyl‐DHP) reagents that besides being as reservoirs, they also enabled conversion adducts to anion intermediates via reduction. Under “catalyst‐oxidant‐additive free” conditions, a wide range structurally different acyl hydrazide products were readily obtained in 56%—99% yields. The utility this transformation further demonstrated by scale‐up synthesis and downstream derivatization.

Language: Английский

Citations

7
Photostimulus-responsive Non-covalent Interactions in Polymers: A Review DOI

Phakamat Limarun,

Kwanchai Buaksuntear,

Siriwan Jansrinak

et al.

Chinese Journal of Polymer Science, Journal Year: 2025, Volume and Issue: unknown

Published: March 13, 2025

Language: Английский

Citations

0
Molecular Imprinting Strategy Enables Circularly Polarized Luminescence Enhancement of Recyclable Chiral Polymer Films DOI

Nianwei Wang,

Ran Hong, Gong Zhang

et al.

Small, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 17, 2024

Circularly polarized luminescence (CPL) plays a crucial role in the fields of optical display and information technology. The pursuit high dissymmetry factors (g

Language: Английский

Citations

3
New Concept on the Generation and Regulation of Circularly Polarized Luminescence DOI Open Access
Gong Zhang, Wei Zhang

Chemistry - A European Journal, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 12, 2024

Circularly polarized luminescence (CPL) has attracted tremendous attention because of its significant application prospect across multiple fields three-dimensional display, data storage, and information encryption. Chirality are two necessary prerequisites for the generation CPL. However, controlling these factors simultaneously in a rational manner remains challenge. Herein, we highlight recent advances on regulation CPL through new concept, named matching rules, mainly including fluorescence-selective absorption, circularly fluorescence energy transfer, chiral communication between excited state ground state. An important commonality among strategies is that they need good overlap corresponding spectra luminescent part (fluorescence, phosphorescence, or CPL) (organic, inorganic, organic-inorganic hybrid materials), which can be contactless separate. Different from most previous studies, no covalent noncovalent interactions parts required, makes them more facile convenient. Finally, summarize main advantages current challenges. We expect this concept to offer insightful novel understanding inspiration regulation.

Language: Английский

Citations

0